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- W1965748949 abstract "(S)-(-)-Paraconic acid (1) was prepared from 2-(acetoxymethyl)-3-phenylpropyl acetate (4) by its asymmetric hydrolysis with pig pancreatic lipase as the key step. Similarly, (R)-(+)-1 was prepared from 2-(acetoxymethyl)-4-pentenyl acetate (2) by its asymmetric hydrolysis with lipase MY. Präparative Bioorganische Chemie, XI. – Darstellung der Enantiomeren von Paraconsäure durch Lipase-katalysierte asymmetrische Hydrolyse von prochiralen Diacetaten als Schlüsselschritt Es wird die Darstellung von (S)-(-)-Paraconsäure (1) aus [2-(Acetoxymethyl)-3-phenylpropyl]acetat (4) durch dessen asymmetrische Hydrolyse mit Schweine-Pankreas-Lipase als Schlüsselreaktion beschrieben. Ähnlich erhält man (R)-(+)-1 aus [2-(Acetoxymethyl)-4-pentenyl]acetat (2) durch dessen Hydrolyse mit Lipase MY." @default.
- W1965748949 created "2016-06-24" @default.
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- W1965748949 date "1989-10-13" @default.
- W1965748949 modified "2023-10-14" @default.
- W1965748949 title "Preparative Bioorganic Chemistry, XI Preparation of the Enantiomers of Paraconic Acid Employing Lipase-Mediated Asymmetric Hydrolysis of Prochiral Diacetates as the Key Step" @default.
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- W1965748949 doi "https://doi.org/10.1002/jlac.198919890251" @default.
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