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- W1965750234 endingPage "3596" @default.
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- W1965750234 abstract "Mechanistic work on the olefin metathesis reaction by well-characterized ruthenium carbene complexes led to the rational design and synthesis of a modified, unsymmetrical “first-generation” catalyst, which, in contrast to either first- or second-generation systems with symmetrical ligands, converts a mixture of two cycloolefin monomers to a largely alternating copolymer. The mechanistic concept of a homogeneous catalyst that switches between more than one state at each turnover is general. The structures of the complexes, determined by mass spectrometry, NMR, and X-ray crystallography, reveal some unexpected features, which explain sequence errors in the copolymer." @default.
- W1965750234 created "2016-06-24" @default.
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- W1965750234 date "2007-06-09" @default.
- W1965750234 modified "2023-10-15" @default.
- W1965750234 title "Mechanistically Designed Dual-Site Catalysts for the Alternating ROMP of Norbornene and Cyclooctene" @default.
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- W1965750234 doi "https://doi.org/10.1021/om700321a" @default.
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