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- W1965804292 abstract "Abstract cis ‐3‐Benzyloxy‐4‐(2‐bromo‐1,1‐dimethylethyl)azetidin‐2‐ones were transformed into the corresponding 3‐hydroxy‐β‐lactams through hydrogenolysis of the benzyl ether substituent, followed by formation of novel cis ‐2‐oxa‐6‐azabicyclo[3.2.0]heptan‐7‐ones by intramolecular nucleophilic substitution utilizing triethylamine in benzene. The conversion of the latter cis ‐2‐oxa‐6‐azabicyclo[3.2.0]heptan‐7‐ones into cis ‐3‐aminotetrahydrofuran‐2‐carboxylates was accomplished by means of acidic methanolysis. In this paper, the first straightforward transformation of cis ‐azetidin‐2‐ones into cis ‐3‐aminotetrahydrofuran‐2‐carboxylates via bicyclic β‐lactams is reported." @default.
- W1965804292 created "2016-06-24" @default.
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- W1965804292 date "2009-12-22" @default.
- W1965804292 modified "2023-10-17" @default.
- W1965804292 title "Synthesis of 3,4‐Fused Bicyclic β‐Lactams and Their Transformation into Methyl <i>cis</i>‐3‐Aminotetrahydrofuran‐2‐carboxylates" @default.
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- W1965804292 doi "https://doi.org/10.1002/ejoc.200901110" @default.
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