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- W1965807372 abstract "The syntheses and properties of corannulenes carrying electron-withdrawing groups (F, CF3 , C6 F5 ) are reported. Direct fluorination of corannulene (C20 H10 ) was carried out with xenon difluoride, and the crystal structure of the product was confirmed by the X-ray analysis. Novel trifluoromethylated corannulenes, including the versatile 4,9-dibromo-1,2-bis(trifluoromethyl)corannulene, were obtained by various established ring-closing reactions. Besides the use of hexafluorobutyne for the construction of fluoranthenes by Diels-Alder reaction as precursor molecules to form 1,2-disubstituted corannulenes, bis(pentafluorophenyl)acetylene was employed as dienophile. The molecular structure and crystal packing of a trifluoromethylated corannulene was determined by single-crystal X-ray analysis and compared with those known brominated and trifluoromethylated corannulenes. The general electron-acceptor properties of corannulenes bearing substituents introduced in particular positions by liquid-phase synthesis are discussed together with published computational results." @default.
- W1965807372 created "2016-06-24" @default.
- W1965807372 creator A5011874515 @default.
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- W1965807372 date "2013-09-05" @default.
- W1965807372 modified "2023-10-07" @default.
- W1965807372 title "Fluorinated and Trifluoromethylated Corannulenes" @default.
- W1965807372 cites W1963918202 @default.
- W1965807372 cites W1965068569 @default.
- W1965807372 cites W1969652545 @default.
- W1965807372 cites W1969969248 @default.
- W1965807372 cites W1972931609 @default.
- W1965807372 cites W1974734160 @default.
- W1965807372 cites W1975974249 @default.
- W1965807372 cites W1977038777 @default.
- W1965807372 cites W1978390512 @default.
- W1965807372 cites W1979368277 @default.
- W1965807372 cites W1980237538 @default.
- W1965807372 cites W1981765155 @default.
- W1965807372 cites W1982644864 @default.
- W1965807372 cites W1982957864 @default.
- W1965807372 cites W1987918731 @default.
- W1965807372 cites W1988950864 @default.
- W1965807372 cites W1998003598 @default.
- W1965807372 cites W1999626873 @default.
- W1965807372 cites W1999673416 @default.
- W1965807372 cites W2001086298 @default.
- W1965807372 cites W2006099558 @default.
- W1965807372 cites W2009927549 @default.
- W1965807372 cites W2012275970 @default.
- W1965807372 cites W2014393643 @default.
- W1965807372 cites W2014757356 @default.
- W1965807372 cites W2018211590 @default.
- W1965807372 cites W2019153426 @default.
- W1965807372 cites W2024622459 @default.
- W1965807372 cites W2025845665 @default.
- W1965807372 cites W2026879294 @default.
- W1965807372 cites W2028184840 @default.
- W1965807372 cites W2029399759 @default.
- W1965807372 cites W2030695520 @default.
- W1965807372 cites W2031429337 @default.
- W1965807372 cites W2031730820 @default.
- W1965807372 cites W2032183911 @default.
- W1965807372 cites W2033043158 @default.
- W1965807372 cites W2037544448 @default.
- W1965807372 cites W2038297681 @default.
- W1965807372 cites W2051441149 @default.
- W1965807372 cites W2053873979 @default.
- W1965807372 cites W2054805738 @default.
- W1965807372 cites W2057547754 @default.
- W1965807372 cites W2061899554 @default.
- W1965807372 cites W2061987960 @default.
- W1965807372 cites W2065730920 @default.
- W1965807372 cites W2072918001 @default.
- W1965807372 cites W2080335766 @default.
- W1965807372 cites W2088222298 @default.
- W1965807372 cites W2088764599 @default.
- W1965807372 cites W2093137710 @default.
- W1965807372 cites W2093817230 @default.
- W1965807372 cites W2096422651 @default.
- W1965807372 cites W2097913943 @default.
- W1965807372 cites W2113701650 @default.
- W1965807372 cites W2116193306 @default.
- W1965807372 cites W2117924652 @default.
- W1965807372 cites W2124229280 @default.
- W1965807372 cites W2128995997 @default.
- W1965807372 cites W2130743598 @default.
- W1965807372 cites W2131350133 @default.
- W1965807372 cites W2131542594 @default.
- W1965807372 cites W2131573649 @default.
- W1965807372 cites W2138013690 @default.
- W1965807372 cites W2138771320 @default.
- W1965807372 cites W2141471401 @default.
- W1965807372 cites W2143093579 @default.
- W1965807372 cites W2144869962 @default.
- W1965807372 cites W2151190614 @default.
- W1965807372 cites W2156739932 @default.
- W1965807372 cites W2163652218 @default.
- W1965807372 cites W2171356682 @default.
- W1965807372 cites W2172688550 @default.
- W1965807372 cites W2181127700 @default.
- W1965807372 cites W2316683099 @default.
- W1965807372 cites W2317659903 @default.
- W1965807372 cites W2321939844 @default.
- W1965807372 cites W2324572467 @default.
- W1965807372 cites W2325831907 @default.
- W1965807372 cites W2326103891 @default.
- W1965807372 cites W2331213730 @default.
- W1965807372 cites W2515615365 @default.
- W1965807372 cites W2950844313 @default.
- W1965807372 cites W2950991474 @default.
- W1965807372 cites W2951311958 @default.
- W1965807372 cites W4229993555 @default.