Matches in SemOpenAlex for { <https://semopenalex.org/work/W1965864327> ?p ?o ?g. }
- W1965864327 abstract "The radiolysis of nitrile rubbers with different acrylonitrile/butadiene composition and the homopolymers, poly(butadiene) (PBD) and poly(acrylonitrile) (PAN) has been investigated and compared with the photolysis of the same polymers. A significantly different mechanism of degradation was found for the two types of radiation. The results obtained by ESR, FTIR and measurements of soluble fractions of irradiated samples, indicated that the acrylonitrile units of the nitrile rubbers are more sensitive units to gamma-radiation, with the effects of irradiation increasing with the acrylonitrile content. The reactions observed were consumption of double bonds, crosslinking, and cyclization with the formation of conjugated double bonds. No chain-scission reactions were detected. In contrast to gamma-irradiation, the effects of photolysis were centred at the butadiene units, and increases in the acrylonitrile content resulted in a proportional decrease in the sensitivity of the copolymers. Crosslinking and chain scission were identified as the main effects of photolysis of NBR rubbers. (C) 1999 Society of Chemical Industry." @default.
- W1965864327 created "2016-06-24" @default.
- W1965864327 creator A5000851503 @default.
- W1965864327 creator A5014423314 @default.
- W1965864327 creator A5034029583 @default.
- W1965864327 creator A5062273177 @default.
- W1965864327 date "1999-10-01" @default.
- W1965864327 modified "2023-09-23" @default.
- W1965864327 title "A comparative study of the effects of UV- and γ-radiation on copolymers of acrylonitrile/butadiene" @default.
- W1965864327 cites W1976979638 @default.
- W1965864327 cites W1981420015 @default.
- W1965864327 cites W1988735544 @default.
- W1965864327 cites W1988800608 @default.
- W1965864327 cites W1991554412 @default.
- W1965864327 cites W1997117043 @default.
- W1965864327 cites W2000003509 @default.
- W1965864327 cites W2009231553 @default.
- W1965864327 cites W2013382925 @default.
- W1965864327 cites W2034588074 @default.
- W1965864327 cites W2044678475 @default.
- W1965864327 cites W2045948357 @default.
- W1965864327 cites W2068083644 @default.
- W1965864327 cites W2073644384 @default.
- W1965864327 cites W2078995796 @default.
- W1965864327 cites W2080397473 @default.
- W1965864327 cites W2090956170 @default.
- W1965864327 cites W2155909140 @default.
- W1965864327 cites W2166206309 @default.
- W1965864327 cites W2169476871 @default.
- W1965864327 cites W4206824152 @default.
- W1965864327 doi "https://doi.org/10.1002/(sici)1097-0126(199910)48:10<985::aid-pi258>3.0.co;2-3" @default.
- W1965864327 hasPublicationYear "1999" @default.
- W1965864327 type Work @default.
- W1965864327 sameAs 1965864327 @default.
- W1965864327 citedByCount "15" @default.
- W1965864327 countsByYear W19658643272012 @default.
- W1965864327 countsByYear W19658643272013 @default.
- W1965864327 countsByYear W19658643272014 @default.
- W1965864327 countsByYear W19658643272015 @default.
- W1965864327 countsByYear W19658643272016 @default.
- W1965864327 countsByYear W19658643272017 @default.
- W1965864327 countsByYear W19658643272018 @default.
- W1965864327 countsByYear W19658643272019 @default.
- W1965864327 countsByYear W19658643272021 @default.
- W1965864327 countsByYear W19658643272022 @default.
- W1965864327 crossrefType "journal-article" @default.
- W1965864327 hasAuthorship W1965864327A5000851503 @default.
- W1965864327 hasAuthorship W1965864327A5014423314 @default.
- W1965864327 hasAuthorship W1965864327A5034029583 @default.
- W1965864327 hasAuthorship W1965864327A5062273177 @default.
- W1965864327 hasConcept C111337013 @default.
- W1965864327 hasConcept C121332964 @default.
- W1965864327 hasConcept C127413603 @default.
- W1965864327 hasConcept C139066938 @default.
- W1965864327 hasConcept C15920480 @default.
- W1965864327 hasConcept C160892712 @default.
- W1965864327 hasConcept C161790260 @default.
- W1965864327 hasConcept C176933379 @default.
- W1965864327 hasConcept C178790620 @default.
- W1965864327 hasConcept C185544564 @default.
- W1965864327 hasConcept C185592680 @default.
- W1965864327 hasConcept C188027245 @default.
- W1965864327 hasConcept C192562407 @default.
- W1965864327 hasConcept C2777133900 @default.
- W1965864327 hasConcept C2778372188 @default.
- W1965864327 hasConcept C2779240715 @default.
- W1965864327 hasConcept C2781161111 @default.
- W1965864327 hasConcept C3044715 @default.
- W1965864327 hasConcept C42360764 @default.
- W1965864327 hasConcept C521977710 @default.
- W1965864327 hasConcept C54582936 @default.
- W1965864327 hasConcept C66887884 @default.
- W1965864327 hasConcept C68381374 @default.
- W1965864327 hasConcept C75473681 @default.
- W1965864327 hasConceptScore W1965864327C111337013 @default.
- W1965864327 hasConceptScore W1965864327C121332964 @default.
- W1965864327 hasConceptScore W1965864327C127413603 @default.
- W1965864327 hasConceptScore W1965864327C139066938 @default.
- W1965864327 hasConceptScore W1965864327C15920480 @default.
- W1965864327 hasConceptScore W1965864327C160892712 @default.
- W1965864327 hasConceptScore W1965864327C161790260 @default.
- W1965864327 hasConceptScore W1965864327C176933379 @default.
- W1965864327 hasConceptScore W1965864327C178790620 @default.
- W1965864327 hasConceptScore W1965864327C185544564 @default.
- W1965864327 hasConceptScore W1965864327C185592680 @default.
- W1965864327 hasConceptScore W1965864327C188027245 @default.
- W1965864327 hasConceptScore W1965864327C192562407 @default.
- W1965864327 hasConceptScore W1965864327C2777133900 @default.
- W1965864327 hasConceptScore W1965864327C2778372188 @default.
- W1965864327 hasConceptScore W1965864327C2779240715 @default.
- W1965864327 hasConceptScore W1965864327C2781161111 @default.
- W1965864327 hasConceptScore W1965864327C3044715 @default.
- W1965864327 hasConceptScore W1965864327C42360764 @default.
- W1965864327 hasConceptScore W1965864327C521977710 @default.
- W1965864327 hasConceptScore W1965864327C54582936 @default.
- W1965864327 hasConceptScore W1965864327C66887884 @default.
- W1965864327 hasConceptScore W1965864327C68381374 @default.
- W1965864327 hasConceptScore W1965864327C75473681 @default.
- W1965864327 hasLocation W19658643271 @default.
- W1965864327 hasOpenAccess W1965864327 @default.