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- W1965872142 abstract "Abstract The EPR study of high quality mixed crystal K(ND 4 )Zn(SO 4 ) 2 6D 2 O shows that the doped 63 Cu(D 2 O) 6 complexes exist simultaneously in two configurations, differing by the directions of Jahn–Teller spontaneous deformation. This observation directly confirms the early supposition that the elongation direction of the doped copper complexes is determined by the indirectly interacting monovalent cations. The high temperature EPR spectra have a ‘powder-like’ appearance and, at lower temperatures, a significant deformation of the resonant lines is observed. These effects are explained as a result of random deformations, introduced by the mixing of ND 4 + and K + ions on the electronic structure and dynamics of the Jahn–Teller hexaaqua copper complexes. Internal deformations change the complex rhombicity and parameters of the Jahn–Teller adiabatic potential leading to their random spread. It is shown that in a low symmetry case, the statistic, symmetrical distributions of these parameters may lead to the asymmetric distribution of g - and A -values, resulting in the asymmetric distribution of the EPR resonant fields. The proposed approach is confirmed by the presentation of theoretical spectra calculated for the assumptions of randomly distributed EPR spectra parameters. These spectra reproduce well experimentally observed spectra in K(ND 4 )Zn(SO 4 ) 2 6D 2 O crystals." @default.
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- W1965872142 date "2001-07-01" @default.
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- W1965872142 title "Effects of ‘random deformations’ in the EPR spectra of Jahn–Teller Cu(D2O)6 complexes in the mixed KND4Zn(SO4)26D2O Tutton salt" @default.
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- W1965872142 doi "https://doi.org/10.1016/s0022-3697(01)00027-0" @default.
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