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- W1965877388 abstract "The reduction of oxidized P-450 by dithionite gives a hyperbolic curve on semilog paper as does the formation of the CO complex of reduced P-450. Reduction of the oxidized P-450-phenylisocyanide complex is pseudo first order. The NADPH dependent oxygen consumption of microsomes is inhibited by cyanide and is correlated with the extent of modification in the ESR spectrum of cytochrome P-450. These results suggest that the reduction of the oxidized P-450 is a two-step reaction via an intermediate state in which the oxygen consumption by microsomes in the presence of NADPH is mainly due to the oxidase action of P-450. We therefore propose a bifunctional feature of the P-450 cytochrome, hydroxylase and oxidase activities." @default.
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- W1965877388 date "1971-08-01" @default.
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- W1965877388 title "Oxidation-reduction mechanisms of cytochrome P-450" @default.
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- W1965877388 doi "https://doi.org/10.1016/s0006-291x(71)80120-1" @default.
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