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• W1965892912 abstract "We report capillary force induced instability from drying water swollen poly(2-hydroxyethyl methacrylate) (PHEMA) based hydrogel membranes with micron-sized holes in a square array. When the PHEMA membrane was exposed to deionized-water, the size of the holes became smaller but retained the shape, so-called breathing mode instability. However, during the drying process, the square pore array buckled into a diamond plate pattern. The deformed pattern could be recovered upon re-exposure to water. The instability mechanism was confirmed by comparing the observations from optical and scanning electron microscopy (SEM) images with theoretical prediction. When thermoresponsive poly(N-isopropylacrylamide) was introduced to the PHEMA gel, the poly(2-hydroxyethyl methacrylate-co-N-isopropylacrylamide) (PHEMA-co-PNIPAAm) membrane underwent pattern transformation only if dried below the lower critical solution temperature of PNIPAAm. Along the pattern transformation, we observed a dramatic change of the optical property of the film, from colourful reflection to transparent window." @default.
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• W1965892912 date "2012-01-01" @default.
• W1965892912 modified "2023-09-26" @default.
• W1965892912 title "Capillarity induced instability in responsive hydrogel membranes with periodic hole array" @default.
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• W1965892912 doi "https://doi.org/10.1039/c2sm25393c" @default.
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