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• W1965893502 abstract "Abstract The conformational analysis of the mesomorphic phase structure in poly(ethylene terephthalate) (PET) films based on the determination of the amount of Ta (trans in the amorphous phase), Tc (trans in the crystalline phase), and G (gauche) isomers present in samples of PET films heat treated between 110°C and 230°C is presented. The change in the amount of isomers was related to the mesomorphic phase determined from a correlation among wide-angle X-ray diffraction (WAXD), Fourier transform infrared (FTIR), density, and sorption properties. The reduction in sorption in semicrystalline samples, with respect to completely amorphous samples, at low penetrant activity allowed determination of the fraction of impermeable phase. This fraction, when compared with crystallinity determined from WAXD and density techniques, is higher, indicating the presence of mesomorphic fractions that probably have a bidimensional order. Separation of the contribution of isomers Ta and Tc and its relation with the mesomorp..." @default.
• W1965893502 created "2016-06-24" @default.
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• W1965893502 date "1999-05-01" @default.
• W1965893502 modified "2023-10-18" @default.
• W1965893502 title "The mesomorphic phase structure in PET films: A conformational analysis" @default.
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• W1965893502 doi "https://doi.org/10.1080/00222349908212433" @default.
• W1965893502 hasPublicationYear "1999" @default.
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