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- W1965895519 abstract "A Ca2+ sensor based on the admittance change of synthetic membranes supported on derivatized silicon electrodes is reported. The ion-sensitive membranes consist of mixed monolayers of phospholipid and the Ca2+-ligand ETH 1001. The electrodes are characterized electrochemically and their sensor performances are described. Through ion complexation by the neutral ligand, electrical charges are incorporated in the low-dielectric-constant environment of the sensitive layer. The number of charged complexes and thus the membrane admittance depend on the ion content of the electrolyte. The membrane response to Ca2+ and the competitive binding of other cations are studied. A non-competitive process is observed if several ionophores, each one specific for a different ion, are incorporated in the membrane. Mixed layers with tetradecyl-18-crown-6 and ETH 1001 show both K+ and Ca2+ sensitivity. These electrodes allow direct comparison with a previously reported K+ sensor based on tetradecyl-18-crown-6." @default.
- W1965895519 created "2016-06-24" @default.
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- W1965895519 date "1992-05-01" @default.
- W1965895519 modified "2023-10-18" @default.
- W1965895519 title "Ca2+-sensitive monolayer electrodes" @default.
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- W1965895519 doi "https://doi.org/10.1016/0022-0728(92)80510-b" @default.
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