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- W1965897516 abstract "Diene-Catalyzed Photodimerization via Excimers (Exciplexes) or Diene Addition to Anthracene and 9-Phenylanthracene The [4 + 4]-photodimerization of anthracene (1) is not enhanced by 2,4-hexadiene (3) but impeded due to formation of [4 + 2]- (4) and [4 + 4]-adducts (5, 6). 6 and 1 combine to give the bisadduct 7 at room temperature. The selective photolysis of 9-phenylanthracene (8) leads to the anti-[4 + 4]-dimer (9). This can be compared with the [4 + 4]-photodimerization of 9-methylanthracene which affords the anti- and the thermolabile syn-product. 1,3-Dienes such as 1,3-pentadiene (10) or 1,3-cyclohexadiene (13) are not necessary for the formation of 9 but undergo cycloadditions with 8 to yield [4 + 2]- (11, 12, 14), [4 + 4]- (15), and [2 + 2]-adducts (16, 17). The structures of the products are established primarily by high field 1H-NMR spectroscopy." @default.
- W1965897516 created "2016-06-24" @default.
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- W1965897516 date "1980-11-01" @default.
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- W1965897516 title "Dien‐katalysierte Photo‐Dimerisierung über Excimere (Exciplexe) oder Dienaddition an Anthracen und 9‐Phenylanthracen?" @default.
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- W1965897516 doi "https://doi.org/10.1002/cber.19801131126" @default.
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