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- W1965938493 abstract "Abstract As a result of screening 19 enzymes, lipase AK (a lipase from Pseudomonas sp.) was found to be suitable for the optical resolution of 2,2,2-trifluoro-1-(indole-3-)ethanol (TFIE). The combination of two lipase AK-catalyzed reactions gave S -(+)-TFIE and R -(−)-TFIE with 97% e.e. and 95% e.e., respectively. The conditions determined as optimum for the reactions were in octane at 45°C for 8 h, and using vinyl acetate for acetylation and using propanol for alcoholysis. In cases of TFIEs with a methyl group on the indole nucleus, the enantioselectivity of lipase AK increases when the methyl group is far from the chiral center." @default.
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- W1965938493 date "1994-01-01" @default.
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- W1965938493 title "Lipase-catalyzed optical resolution of 2,2,2-trifluoro-1-(indole-3-)ethanols in organic solvents" @default.
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- W1965938493 doi "https://doi.org/10.1016/0922-338x(94)90180-5" @default.
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