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- W1965957396 abstract "The silver chalcogenides α′-Ag2 + δTe and β-Ag2 + δSe represent two contrary examples regarding the composition dependence of the chemical diffusion coefficient. Whereas in the vicinity of the stoichiometric composition the coulometric titration curve of β-Ag2Se is determined by the chemical potential of the silver ions (due to its cationic Frenkel disorder), the coulometric titration curve of α-Ag2Te is determined by the chemical potentials of the electrons (due to its structural disorder). The experimentally determined maximum of the chemical diffusion coefficient, in the case of α-Ag2 + δTe, near the stoichiometric point as well as the monotonie decrease of the chemical diffusion coefficient with decreasing silver activity in the case of β-Ag2 + δSe, can be explained in detail." @default.
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- W1965957396 date "1997-02-01" @default.
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- W1965957396 title "Chemical diffusion in mixed conductors: α′-Ag2Te and β-Ag2Se" @default.
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- W1965957396 doi "https://doi.org/10.1016/s0167-2738(96)00584-x" @default.
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