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- W1965967182 abstract "Water-miscibility of some glycol ethers, alkyl phosphates, and TBPO has been determinedin a temperature range of 278-333 K. Solubility isotherms and phase relations have been measured for the ternary systems, salt-water-organic liquid. TMP, TEP, and TEGBE are miscible with water in the temperature range. TBPO, EGBE and DEGHE are partially water-miscible and have LCST of 286 K, 322 K and 298 K respectively.Mutual solubility of the solvent mixtures is sensitive to salt concentration; salt effect enlarges miscibility gaps in the partially miscible systems; TMP-water mixture with sulfate shows a lower consolute temperature. Salts are concentrated into a water-rich phase or crystallized in a homogeneous region, depending on the composition of solutions.Characteristics of these mixtures may be applicable to the processes for purification of waste water, or recovery of metals from dilute solutions. The organic liquid used can be recovered by a small change in temperature or salting-out process from the aqueous solutions. The watermiscible solvents are also separated from solutions by extraction with another organic liquid having temperature-sensitive mutual solubility." @default.
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- W1965967182 date "1994-01-01" @default.
- W1965967182 modified "2023-09-26" @default.
- W1965967182 title "Partial Water-Miscibility of Some Organic Liquids and Application to Separation Processes." @default.
- W1965967182 doi "https://doi.org/10.2473/shigentosozai.110.707" @default.
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