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- W1965984957 abstract "The compounds [MBr2(L)2] (where M is Mn(II), Fe(II), Co(II), Ni(II), Cu(II) or Zn(II); L=β-picoline N-oxide (β-picoNO)) were synthesized and characterized by melting points, elemental analysis, thermal analysis and electronic and IR spectroscopy. The enthalpies of dissolution of the adducts, metal(II) bromides and β-picoNO in methanol or aqueous 1.2 M HCl were measured and by using thermochemical cycles, the following thermochemical parameters for the adducts, have been determined: the standard enthalpies for the Lewis acid/base reactions (ΔrH°), the standard enthalpies of formation (ΔfH°), the standard enthalpies of decomposition (ΔDH°), the lattice standard enthalpies (ΔMH°) and the standard enthalpies of the Lewis acid/base reactions in the gaseous phase (ΔrH°(g)). The mean bond dissociation enthalpies of the metal(II)oxygen bonds (D̄(MO)) have been estimated." @default.
- W1965984957 created "2016-06-24" @default.
- W1965984957 creator A5029489151 @default.
- W1965984957 date "2004-09-01" @default.
- W1965984957 modified "2023-10-02" @default.
- W1965984957 title "Thermochemistry of adducts of some bivalent transition metal bromides with β-picoline N-oxide" @default.
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- W1965984957 doi "https://doi.org/10.1016/j.tca.2004.01.031" @default.
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