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- W1966006082 abstract "In broken chloroplasts the presence of 100 mM sodium formate at pH 8.2 will specifically lengthen the Photosystem II relaxation times of the reactions S′2 → S3 and S′3 → S0. Rates of reactions S′0 → S1 and S′1 → S2 remain unaffected. Evidence is presented which indicates the discrimination among S-states by formate cannot be attributed to a block imposed on the reducing side of Photosystem II. The results are interpreted in context of the known interaction of formate and CO2 which is bound to the Photosystem II reaction center complex. It is proposed that those S-state transitions which show extended relaxation times in the presence of formate must result in the momentary release and rebinding of CO2. Furthermore since formate is acting on the oxygen-evolving side of Photosystem II, it would seem that CO2 is released in reactions that occur there. A chemical model of oxygen evolution is presented. It is based on the hypothesis that hydrated CO2 is the immediate source of photosynthetically evolved oxygen and explains why, under certain conditions formate slows only the S-state transitions S′2 → S3 and S′3 → S0." @default.
- W1966006082 created "2016-06-24" @default.
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- W1966006082 date "1980-11-01" @default.
- W1966006082 modified "2023-09-25" @default.
- W1966006082 title "Inhibition of Photosystem II by formate. Possible evidence for a direct role of bicarbonate in photosynthetic oxygen evolution" @default.
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- W1966006082 doi "https://doi.org/10.1016/0005-2728(80)90011-0" @default.
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