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- W1966012775 abstract "Si-Ge composites have recently been explored as an anode material for lithium-ion batteries due to their stable cycle performance and excellent rate capability. Although previous reports show the benefits of Si-Ge composites on electrochemical performance, the specific mechanism and structural effects have been overlooked. Here, the structural effect of Si-Ge heterogeneous nanostructures on both mechanics and kinetics is systematically studied through theoretical analysis and detailed experimental results. Si-Ge and Ge-Si core–shell nanowires are employed for this study. The Si-Ge core–shell nanowires show a much improved electrochemical performance, especially cycle performance and rate capability, when compared to those of the Ge-Si core–shell nanowires electrode. On the basis of the detailed experimental results and associated theoretical analysis, its is demonstrated that the strain distribution and Li diffusivity and/or diffusion path are significantly affected by the Si-Ge heterostructure, which induce different mechanics and kinetics associated with lithium." @default.
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- W1966012775 date "2013-10-17" @default.
- W1966012775 modified "2023-09-30" @default.
- W1966012775 title "Electrochemical Properties of Si-Ge Heterostructures as an Anode Material for Lithium Ion Batteries" @default.
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- W1966012775 doi "https://doi.org/10.1002/adfm.201302122" @default.
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