Matches in SemOpenAlex for { <https://semopenalex.org/work/W1966071805> ?p ?o ?g. }
Showing items 1 to 99 of
99
with 100 items per page.
- W1966071805 endingPage "26" @default.
- W1966071805 startingPage "23" @default.
- W1966071805 abstract "In this study, the urethane reaction of several phenols with isocyanate was monitored with in-situ FT-IR. Reaction rate constants were calculated out to investigate the effect of substituents in phenols, as well as the polarity of different solvents. It showed that the polarity of solvents largely affected the reaction rate even without catalyst. The reactivity increased in the following order: Xylene < 1,4-Dioxane < Cyclohexanone. Furthermore, an electron-withdrawing substituent in phenols increased the reactivity of hydroxyl with isocyanate. The reason may be that the H-O bond in phenols could be easily polarized under the influence of electron-withdrawing substituent, where the hydrogen atom was more likely to attack the nitrogen atom of -NCO, thus the nucleophilic addition happened easier." @default.
- W1966071805 created "2016-06-24" @default.
- W1966071805 creator A5022177951 @default.
- W1966071805 creator A5038193674 @default.
- W1966071805 creator A5045088910 @default.
- W1966071805 date "2010-10-01" @default.
- W1966071805 modified "2023-09-25" @default.
- W1966071805 title "Effect of Substituents and Solvents on Phenol-Isocyanate Urethane Reaction" @default.
- W1966071805 cites W1921721135 @default.
- W1966071805 cites W1970070244 @default.
- W1966071805 cites W1973609469 @default.
- W1966071805 cites W1992741397 @default.
- W1966071805 cites W1998755504 @default.
- W1966071805 cites W2043011968 @default.
- W1966071805 cites W2048800416 @default.
- W1966071805 cites W2053258469 @default.
- W1966071805 cites W2063204062 @default.
- W1966071805 cites W2071274838 @default.
- W1966071805 cites W2080420770 @default.
- W1966071805 cites W2093355605 @default.
- W1966071805 cites W2094734336 @default.
- W1966071805 cites W2109792192 @default.
- W1966071805 cites W2334514029 @default.
- W1966071805 doi "https://doi.org/10.4028/www.scientific.net/amr.150-151.23" @default.
- W1966071805 hasPublicationYear "2010" @default.
- W1966071805 type Work @default.
- W1966071805 sameAs 1966071805 @default.
- W1966071805 citedByCount "3" @default.
- W1966071805 countsByYear W19660718052013 @default.
- W1966071805 countsByYear W19660718052020 @default.
- W1966071805 countsByYear W19660718052022 @default.
- W1966071805 crossrefType "journal-article" @default.
- W1966071805 hasAuthorship W1966071805A5022177951 @default.
- W1966071805 hasAuthorship W1966071805A5038193674 @default.
- W1966071805 hasAuthorship W1966071805A5045088910 @default.
- W1966071805 hasConcept C121332964 @default.
- W1966071805 hasConcept C142724271 @default.
- W1966071805 hasConcept C148898269 @default.
- W1966071805 hasConcept C155647269 @default.
- W1966071805 hasConcept C161790260 @default.
- W1966071805 hasConcept C178790620 @default.
- W1966071805 hasConcept C178907741 @default.
- W1966071805 hasConcept C185592680 @default.
- W1966071805 hasConcept C188027245 @default.
- W1966071805 hasConcept C204787440 @default.
- W1966071805 hasConcept C2776910235 @default.
- W1966071805 hasConcept C2777702071 @default.
- W1966071805 hasConcept C2777728882 @default.
- W1966071805 hasConcept C2778689049 @default.
- W1966071805 hasConcept C2779578285 @default.
- W1966071805 hasConcept C2780450521 @default.
- W1966071805 hasConcept C2780534471 @default.
- W1966071805 hasConcept C35396096 @default.
- W1966071805 hasConcept C62520636 @default.
- W1966071805 hasConcept C71924100 @default.
- W1966071805 hasConcept C75473681 @default.
- W1966071805 hasConcept C93391505 @default.
- W1966071805 hasConceptScore W1966071805C121332964 @default.
- W1966071805 hasConceptScore W1966071805C142724271 @default.
- W1966071805 hasConceptScore W1966071805C148898269 @default.
- W1966071805 hasConceptScore W1966071805C155647269 @default.
- W1966071805 hasConceptScore W1966071805C161790260 @default.
- W1966071805 hasConceptScore W1966071805C178790620 @default.
- W1966071805 hasConceptScore W1966071805C178907741 @default.
- W1966071805 hasConceptScore W1966071805C185592680 @default.
- W1966071805 hasConceptScore W1966071805C188027245 @default.
- W1966071805 hasConceptScore W1966071805C204787440 @default.
- W1966071805 hasConceptScore W1966071805C2776910235 @default.
- W1966071805 hasConceptScore W1966071805C2777702071 @default.
- W1966071805 hasConceptScore W1966071805C2777728882 @default.
- W1966071805 hasConceptScore W1966071805C2778689049 @default.
- W1966071805 hasConceptScore W1966071805C2779578285 @default.
- W1966071805 hasConceptScore W1966071805C2780450521 @default.
- W1966071805 hasConceptScore W1966071805C2780534471 @default.
- W1966071805 hasConceptScore W1966071805C35396096 @default.
- W1966071805 hasConceptScore W1966071805C62520636 @default.
- W1966071805 hasConceptScore W1966071805C71924100 @default.
- W1966071805 hasConceptScore W1966071805C75473681 @default.
- W1966071805 hasConceptScore W1966071805C93391505 @default.
- W1966071805 hasLocation W19660718051 @default.
- W1966071805 hasOpenAccess W1966071805 @default.
- W1966071805 hasPrimaryLocation W19660718051 @default.
- W1966071805 hasRelatedWork W1966071805 @default.
- W1966071805 hasRelatedWork W2028333188 @default.
- W1966071805 hasRelatedWork W2030908055 @default.
- W1966071805 hasRelatedWork W2089046916 @default.
- W1966071805 hasRelatedWork W2135838290 @default.
- W1966071805 hasRelatedWork W2140136115 @default.
- W1966071805 hasRelatedWork W2149454705 @default.
- W1966071805 hasRelatedWork W2340193433 @default.
- W1966071805 hasRelatedWork W2356710254 @default.
- W1966071805 hasRelatedWork W2951262587 @default.
- W1966071805 hasVolume "150-151" @default.
- W1966071805 isParatext "false" @default.
- W1966071805 isRetracted "false" @default.
- W1966071805 magId "1966071805" @default.
- W1966071805 workType "article" @default.