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- W1966080923 abstract "Abstract Poly[1-acrylamido-2(2-pyridyl)ethane] homopolymer (PAEPH) and polymer complexes of 1-acrylamido-2(2-pyridyl)ethane with a number of bi- and tetravalent transition metals have been prepared and characterized using spectral ( 1 H- and 13 C-NMR, IR, UV-Vis) and thermal analysis, and magnetic measurements. The important bands in the IR spectra and the main 1 H- and 13 C-NMR signals are assigned and discussed in relation to molecular structure. Considerable interest has also been focused on the synthesis of the homopolymer and polymer complexes due to their potential application. Tentative structures for the complexes are proposed. Four types of Zr(IV) polymer complexes were prepared. In type [(A) + (C)] (1:1′ metal:ligand) the chelate rings are five-membered, whereas in type [(B) + (D)] (1:2) they are six-membered. The values of energy of activation of degradation of the compounds were determined from TG and DTA curves." @default.
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- W1966080923 date "1995-01-01" @default.
- W1966080923 modified "2023-09-27" @default.
- W1966080923 title "Polymer complexes. XXIX. Novel polymer complexes prepared from poly(1-acrylamido-2(2-pyridyl)ethane" @default.
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- W1966080923 doi "https://doi.org/10.1016/0141-3910(95)00029-l" @default.
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