Matches in SemOpenAlex for { <https://semopenalex.org/work/W1966098879> ?p ?o ?g. }
- W1966098879 endingPage "1842" @default.
- W1966098879 startingPage "1834" @default.
- W1966098879 abstract "Solvolysis rates of 2-(aryldimethylsilyl)ethyl chlorides were determined conductimetrically in 60% (v/v) aqueous ethanol. The effects of aryl substituents at the silyl atom on the solvolysis rates at 50 °C were correlated with essentially nonresonant parameters of r = 0.10 in terms of Yukawa–Tsuno (Y–T) Eq. 1, giving a ρ value of −1.75. Such a high ρ value may be regarded as the effect of aryl ring on the bridged Si in the rate-determining step. The Si-bridging is consistent with the fact that the solvolysis of the unsubstituted substrate with d2-labeled ethylene moiety gave substitution products with label scrambling. The arylsilyl substituent effects were likewise analyzed for several relevant sets of β-silyl systems in order to ascertain significant variations of ρ values from system to system; Y–T Eq. 1 correlated quite excellently with essentially nonresonant sigmas of negligible resonance demand (r 0.10), to exhibit significant variations of ρ from −1.75 to −0.95." @default.
- W1966098879 created "2016-06-24" @default.
- W1966098879 creator A5002811575 @default.
- W1966098879 creator A5027073820 @default.
- W1966098879 creator A5038332637 @default.
- W1966098879 creator A5039997002 @default.
- W1966098879 creator A5075003140 @default.
- W1966098879 creator A5084447935 @default.
- W1966098879 creator A5086013602 @default.
- W1966098879 date "2005-10-01" @default.
- W1966098879 modified "2023-09-26" @default.
- W1966098879 title "The Yukawa–Tsuno Relationship for the β-Silicon Effect in the Solvolysis Rates of 2-(Aryldimethylsilyl)ethyl Chlorides" @default.
- W1966098879 cites W1532377613 @default.
- W1966098879 cites W1603380508 @default.
- W1966098879 cites W1965491358 @default.
- W1966098879 cites W1971088191 @default.
- W1966098879 cites W1974029971 @default.
- W1966098879 cites W1975457309 @default.
- W1966098879 cites W1976214023 @default.
- W1966098879 cites W1981280557 @default.
- W1966098879 cites W1986484791 @default.
- W1966098879 cites W1989733386 @default.
- W1966098879 cites W1994520625 @default.
- W1966098879 cites W1995602159 @default.
- W1966098879 cites W2003408007 @default.
- W1966098879 cites W2009204807 @default.
- W1966098879 cites W2015948094 @default.
- W1966098879 cites W2020629227 @default.
- W1966098879 cites W2023146112 @default.
- W1966098879 cites W2032898372 @default.
- W1966098879 cites W2052190181 @default.
- W1966098879 cites W2053455159 @default.
- W1966098879 cites W2056745753 @default.
- W1966098879 cites W2056894364 @default.
- W1966098879 cites W2060993888 @default.
- W1966098879 cites W2076197894 @default.
- W1966098879 cites W2093367613 @default.
- W1966098879 cites W2163423978 @default.
- W1966098879 cites W2312855676 @default.
- W1966098879 cites W2314312817 @default.
- W1966098879 cites W2320795774 @default.
- W1966098879 cites W2330417826 @default.
- W1966098879 cites W2335217515 @default.
- W1966098879 cites W2951192521 @default.
- W1966098879 cites W2951865499 @default.
- W1966098879 cites W2953113068 @default.
- W1966098879 cites W1983413041 @default.
- W1966098879 doi "https://doi.org/10.1246/bcsj.78.1834" @default.
- W1966098879 hasPublicationYear "2005" @default.
- W1966098879 type Work @default.
- W1966098879 sameAs 1966098879 @default.
- W1966098879 citedByCount "14" @default.
- W1966098879 countsByYear W19660988792012 @default.
- W1966098879 countsByYear W19660988792018 @default.
- W1966098879 countsByYear W19660988792020 @default.
- W1966098879 crossrefType "journal-article" @default.
- W1966098879 hasAuthorship W1966098879A5002811575 @default.
- W1966098879 hasAuthorship W1966098879A5027073820 @default.
- W1966098879 hasAuthorship W1966098879A5038332637 @default.
- W1966098879 hasAuthorship W1966098879A5039997002 @default.
- W1966098879 hasAuthorship W1966098879A5075003140 @default.
- W1966098879 hasAuthorship W1966098879A5084447935 @default.
- W1966098879 hasAuthorship W1966098879A5086013602 @default.
- W1966098879 hasConcept C109214941 @default.
- W1966098879 hasConcept C121332964 @default.
- W1966098879 hasConcept C147597530 @default.
- W1966098879 hasConcept C151195881 @default.
- W1966098879 hasConcept C155647269 @default.
- W1966098879 hasConcept C161790260 @default.
- W1966098879 hasConcept C178790620 @default.
- W1966098879 hasConcept C184651966 @default.
- W1966098879 hasConcept C185592680 @default.
- W1966098879 hasConcept C2776568683 @default.
- W1966098879 hasConcept C2778689049 @default.
- W1966098879 hasConcept C2779293432 @default.
- W1966098879 hasConcept C2780263894 @default.
- W1966098879 hasConcept C2781076698 @default.
- W1966098879 hasConcept C5304478 @default.
- W1966098879 hasConcept C71240020 @default.
- W1966098879 hasConcept C94412978 @default.
- W1966098879 hasConceptScore W1966098879C109214941 @default.
- W1966098879 hasConceptScore W1966098879C121332964 @default.
- W1966098879 hasConceptScore W1966098879C147597530 @default.
- W1966098879 hasConceptScore W1966098879C151195881 @default.
- W1966098879 hasConceptScore W1966098879C155647269 @default.
- W1966098879 hasConceptScore W1966098879C161790260 @default.
- W1966098879 hasConceptScore W1966098879C178790620 @default.
- W1966098879 hasConceptScore W1966098879C184651966 @default.
- W1966098879 hasConceptScore W1966098879C185592680 @default.
- W1966098879 hasConceptScore W1966098879C2776568683 @default.
- W1966098879 hasConceptScore W1966098879C2778689049 @default.
- W1966098879 hasConceptScore W1966098879C2779293432 @default.
- W1966098879 hasConceptScore W1966098879C2780263894 @default.
- W1966098879 hasConceptScore W1966098879C2781076698 @default.
- W1966098879 hasConceptScore W1966098879C5304478 @default.
- W1966098879 hasConceptScore W1966098879C71240020 @default.
- W1966098879 hasConceptScore W1966098879C94412978 @default.
- W1966098879 hasIssue "10" @default.