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- W1966103622 abstract "A monophoton technique to measure fast luminescence decay and utilizing pulsed uv excitation has been employed to determine specific rates of excitation quenching in systems containing n-nonane+p-xylene+CCl4, with n-nonane serving as an optically inert solvent, p-xylene as scintillator, and CCl4 as quencher. The decay-time data are employed to evaluate the characteristic rate parameters kq for quenching of p-xylene luminescence by CCl4. Values so obtained are in good agreement with values obtained from steady-state studies. The variation in kq with p-xylene concentration is consistent with the view that energy migration as such via p-xylene molecules occurs in addition to material diffusion of excited molecules. Dynamic and steady-state measurements of self-quenching in p-xylene+n-nonane systems indicate that, if excimer formation in p-xylene occurs, it is followed by a very rapid nonradiative deactivation of the excimer. Furthermore, differences in the self-quenching behavior as determined with steady-state and decay-time techniques suggest some form of static quenching in p-xylene. This static quenching can be explained on the basis of clustering in the ground state." @default.
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- W1966103622 date "1967-11-01" @default.
- W1966103622 modified "2023-09-24" @default.
- W1966103622 title "Luminescence Quenching and Decay Processes in Multicomponent Systems: n‐Nonane+p‐Xylene+CCl4" @default.
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- W1966103622 doi "https://doi.org/10.1063/1.1712420" @default.
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