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- W1966103675 abstract "Abstract The heats of formation of alkali halides (CsX, RbX, KX, NaX, LiX) and pseudo-alkali halides (NH 4 X, TlX, CuX, AgX, AuX), −Δ H 0 298 , are empirically expressed by the electronegativities (χ a ) of the halogen ion: where a and b are empirical constants; e , r C and r A represent the charge on the electron, cation radius, and anion radius, respectively. The value of ± e 2 / r (C and/or a) corresponds to the electrostatic energy between the effective nuclear charge of the M + and/or X − ion and an electron at a distance from its nucleus equal to its ionic radius r C and/or r A . The empirical constants a and b correlate with the electronegativity of the M + ion in two different trends; one is the alkali ion series and the other is the pseudo-alkali ion series. This means that Pauling's electronegativities of alkali and pseudo-alkali ions are based on different scales. Assuming that the ( X -IP) correlations for pseudo-alkali ions constitute the same series as the ( χ -IP) correlations for alkali ions, where X is the electronegativity and IP is the first ionization potential, the electronegativities of Tl + , Ag + , Cu + and Au + are changed to 1.1, 1.3, 1.4 and 1.7, respectively, with noticeable error. The value (1.1) for the Tl + ion is consistent with the ionic character of the bonds formed by Tl + in some compounds." @default.
- W1966103675 created "2016-06-24" @default.
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- W1966103675 date "1986-11-01" @default.
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- W1966103675 title "Relation between heats of formation of alkali and pseudo-alkali halides and electronegativities of halogen ions" @default.
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- W1966103675 doi "https://doi.org/10.1016/0040-6031(86)85091-2" @default.
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