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- W1966156837 abstract "Methyl methacrylate/1,2-divinylbenzene (MMA/DVB) in an opaque emulsion were successfully grafted onto the surface of polymeric substrate under the irradiation of UV light with benzophenone (BP) as a photoinitiator that was previously coated on the substrate surface. Monomer conversion, grafting efficiency, and grafting yields were determined by the gravimetric method. ATR-IR, AFM, and TEM were used to characterize the surface composition, to observe the topography of the grafted substrates, and to view inter-film colloid particles formed by cross-linking. The results reveal that, with the opaque MMA/DVB emulsion system and CPP film as substrate, the monomer conversion is in the range of 15-55%, the grafting efficiency is about 80%, the grafting yield reaches 5%, and the thickness of the graft layer can be controlled in the range 0.09-1.5 microm. Images of AFM show that the graft layer is piled up by nanoparticles (about 30-50 nm in diameter), which are linked together and tied to the substrate surface with covalent bonds. A possible model of surface graft polymerization including surface initiating, nucleation, and shish kebab growing is put forward to interpreting the above results." @default.
- W1966156837 created "2016-06-24" @default.
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- W1966156837 date "2004-06-16" @default.
- W1966156837 modified "2023-09-24" @default.
- W1966156837 title "MMA/DVB Emulsion Surface Graft Polymerization Initiated by UV Light" @default.
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- W1966156837 doi "https://doi.org/10.1021/la0493924" @default.
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