FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1966171880> ?p ?o ?g. }

• W1966171880 endingPage "13440" @default.
• W1966171880 startingPage "13430" @default.
• W1966171880 abstract "Calcium is one of the most abundant cations in living organisms. It is found in the mineral phase of bone and in proteins like calmodulin. However, its exact environment beyond the first coordination sphere is often unknown, thus hampering the understanding of many biological processes. Here, calcium benzoate trihydrate (Ca(C(6)H(5)COO)(2) x 3 H(2)O) was used as a model for the NMR analysis of calcium sites in biological materials, because of the similarity of its calcium coordination, to water and carboxylate ligands, to that in several calcium-proteins. First, calcium-43 magic angle spinning (MAS) and static NMR spectra of a (43)Ca enriched sample were recorded at different magnetic fields, to investigate the electronic environment of calcium. Complex static lineshapes were obtained because of the presence of anisotropic NMR interactions of similar magnitude (chemical shift anisotropy and quadrupolar interaction), and the full interpretation of the spectra required simulations and gauge-including projector augmented wave (GIPAW) DFT calculations. An NMR investigation of the coordination environment of Ca(2+) was carried out, using high resolution (13)C-(43)Ca MAS NMR experiments such as TRAPDOR (transfer of population double resonance) and heteronuclear J-spin-echoes. It was shown that despite the weakness of (13)C-(43)Ca interactions, it is possible to discriminate carbon atoms according to their calcium environment. Long-range calcium-carbon correlations were even evidenced by TRAPDOR, reaching distances >5.6 A. This work demonstrates that by combining solid state NMR experiments, DFT calculations, and simulations, it will be possible to elucidate the electronic and coordination environment of calcium in many important and complex materials." @default.
• W1966171880 created "2016-06-24" @default.
• W1966171880 creator A5013553633 @default.
• W1966171880 creator A5017215156 @default.
• W1966171880 creator A5025563035 @default.
• W1966171880 creator A5029810604 @default.
• W1966171880 creator A5054438179 @default.
• W1966171880 creator A5067176316 @default.
• W1966171880 creator A5072087376 @default.
• W1966171880 creator A5072105192 @default.
• W1966171880 date "2009-08-28" @default.
• W1966171880 modified "2023-09-30" @default.
• W1966171880 title "Implementation of High Resolution ⁴³Ca Solid State NMR Spectroscopy: Toward the Elucidation of Calcium Sites in Biological Materials" @default.
• W1966171880 cites W1966742768 @default.
• W1966171880 cites W1966972585 @default.
• W1966171880 cites W1968875604 @default.
• W1966171880 cites W1970658246 @default.
• W1966171880 cites W1972596227 @default.
• W1966171880 cites W1981368803 @default.
• W1966171880 cites W1981591574 @default.
• W1966171880 cites W1981708118 @default.
• W1966171880 cites W1982873992 @default.
• W1966171880 cites W1984700305 @default.
• W1966171880 cites W1985950019 @default.
• W1966171880 cites W1988532478 @default.
• W1966171880 cites W1992836438 @default.
• W1966171880 cites W1992928305 @default.
• W1966171880 cites W1993008730 @default.
• W1966171880 cites W1999092875 @default.
• W1966171880 cites W2005716802 @default.
• W1966171880 cites W2006717254 @default.
• W1966171880 cites W2008585207 @default.
• W1966171880 cites W2011285059 @default.
• W1966171880 cites W2017570090 @default.
• W1966171880 cites W2017851855 @default.
• W1966171880 cites W2022305051 @default.
• W1966171880 cites W2022360060 @default.
• W1966171880 cites W2022461564 @default.
• W1966171880 cites W2026195773 @default.
• W1966171880 cites W2027616725 @default.
• W1966171880 cites W2029169169 @default.
• W1966171880 cites W2032156854 @default.
• W1966171880 cites W2033734487 @default.
• W1966171880 cites W2038877642 @default.
• W1966171880 cites W2039694312 @default.
• W1966171880 cites W2041532104 @default.
• W1966171880 cites W2045596260 @default.
• W1966171880 cites W2045629972 @default.
• W1966171880 cites W2045790328 @default.
• W1966171880 cites W2051716201 @default.
• W1966171880 cites W2055516309 @default.
• W1966171880 cites W2055640329 @default.
• W1966171880 cites W2057603010 @default.
• W1966171880 cites W2061063513 @default.
• W1966171880 cites W2061588056 @default.
• W1966171880 cites W2075954894 @default.
• W1966171880 cites W2080334952 @default.
• W1966171880 cites W2082259056 @default.
• W1966171880 cites W2083094963 @default.
• W1966171880 cites W2087471605 @default.
• W1966171880 cites W2089482739 @default.
• W1966171880 cites W2092976219 @default.
• W1966171880 cites W2107746113 @default.
• W1966171880 cites W2118920918 @default.
• W1966171880 cites W2122687281 @default.
• W1966171880 cites W2123874134 @default.
• W1966171880 cites W2130111075 @default.
• W1966171880 cites W2130971715 @default.
• W1966171880 cites W2134094820 @default.
• W1966171880 cites W2147808349 @default.
• W1966171880 cites W2316660611 @default.
• W1966171880 cites W4235261249 @default.
• W1966171880 cites W4300151547 @default.
• W1966171880 cites W4322696248 @default.
• W1966171880 cites W4362225795 @default.
• W1966171880 cites W819975641 @default.
• W1966171880 doi "https://doi.org/10.1021/ja904553q" @default.
• W1966171880 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/19715269" @default.
• W1966171880 hasPublicationYear "2009" @default.
• W1966171880 type Work @default.
• W1966171880 sameAs 1966171880 @default.
• W1966171880 citedByCount "52" @default.
• W1966171880 countsByYear W19661718802012 @default.
• W1966171880 countsByYear W19661718802013 @default.
• W1966171880 countsByYear W19661718802014 @default.
• W1966171880 countsByYear W19661718802015 @default.
• W1966171880 countsByYear W19661718802016 @default.
• W1966171880 countsByYear W19661718802017 @default.
• W1966171880 countsByYear W19661718802018 @default.
• W1966171880 countsByYear W19661718802019 @default.
• W1966171880 countsByYear W19661718802021 @default.
• W1966171880 countsByYear W19661718802022 @default.
• W1966171880 crossrefType "journal-article" @default.
• W1966171880 hasAuthorship W1966171880A5013553633 @default.
• W1966171880 hasAuthorship W1966171880A5017215156 @default.
• W1966171880 hasAuthorship W1966171880A5025563035 @default.
• W1966171880 hasAuthorship W1966171880A5029810604 @default.
• W1966171880 hasAuthorship W1966171880A5054438179 @default.

• next