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- W1966173624 abstract "Polarisation by cation formation (e.g., by protonation or by oxocarbonium ion formation) exerts a distinct and systematic effect on the selectivity of radical chlorination of aliphatic acids, amines, and alcohols. A qualitative correlation is demonstrated between the magnitude of deshielding of a given proton (as expressed by the downfield shift in the 1H n.m.r. spectrum) and its “deactivation” as indicated by diminished rate of its abstraction by chlorine atoms. A convenient method is described for the preparation of new and known aliphatic mono- and polychloro-amines." @default.
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- W1966173624 date "1967-01-01" @default.
- W1966173624 modified "2023-10-09" @default.
- W1966173624 title "Polarisation by cation formation: a method for influencing the selectivity of radical chlorination" @default.
- W1966173624 doi "https://doi.org/10.1039/j29670001093" @default.
- W1966173624 hasPublicationYear "1967" @default.
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