Matches in SemOpenAlex for { <https://semopenalex.org/work/W1966178520> ?p ?o ?g. }
- W1966178520 endingPage "3509" @default.
- W1966178520 startingPage "3509" @default.
- W1966178520 abstract "The synthesis by electrocrystallization and X-ray crystal structures of two radical cation salts, (BEDT-TTF)6[Cu8(i-mnt)6]·(CH2Cl2)42 and (EDT-TTF)6[Cu8(i-mnt)6] 3 are described. These salts incorporate the isomaleonitriledithiolato–octa-copper(I) complex [Cu8(i-mnt)6]4− as anion and the bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF), or the ethylenedithiotetrathiafulvalene (EDT-TTF) as radical cations. The crystal structure of the starting material (n-Pr4N)4[CuI8(i-mnt)6]·(MeCN)21 is also reported. In 2, organic molecules form isolated fully oxidized (BEDT-TTF)22+ dimers and mixed valence (BEDT-TTF)21+˙ dimers, the latter assembled in chains along the a-axis. The crystal structure of 3 is composed of layers of anions and cations, the latter incorporate fully oxidized (EDT-TTF)22+ dimers and neutral EDT-TTF molecules. For both salts, interactions between organic molecules were rationalized by extended Hückel calculations. 2 exhibits a low conductivity at room temperature. This study shows that metal dithiolate clusters are a new class of anions suitable for the preparation of TTF-based molecular materials." @default.
- W1966178520 created "2016-06-24" @default.
- W1966178520 creator A5001028688 @default.
- W1966178520 creator A5057018652 @default.
- W1966178520 creator A5063594040 @default.
- W1966178520 date "2004-01-01" @default.
- W1966178520 modified "2023-10-01" @default.
- W1966178520 title "Radical cation salts of TTF derivatives incorporating the maleonitriledithiolate copper cluster anion [Cu8(i-mnt)6]4?" @default.
- W1966178520 cites W1530128299 @default.
- W1966178520 cites W1534642195 @default.
- W1966178520 cites W1954985106 @default.
- W1966178520 cites W1964943154 @default.
- W1966178520 cites W1972669157 @default.
- W1966178520 cites W1972719698 @default.
- W1966178520 cites W1977955686 @default.
- W1966178520 cites W1981244598 @default.
- W1966178520 cites W1981458170 @default.
- W1966178520 cites W1983450674 @default.
- W1966178520 cites W1983903380 @default.
- W1966178520 cites W1984231545 @default.
- W1966178520 cites W1989263877 @default.
- W1966178520 cites W1994395973 @default.
- W1966178520 cites W1995712671 @default.
- W1966178520 cites W1997788155 @default.
- W1966178520 cites W2004842014 @default.
- W1966178520 cites W2005619277 @default.
- W1966178520 cites W2019416707 @default.
- W1966178520 cites W2030714366 @default.
- W1966178520 cites W2039279256 @default.
- W1966178520 cites W2039335944 @default.
- W1966178520 cites W2040726862 @default.
- W1966178520 cites W2042403105 @default.
- W1966178520 cites W2043570317 @default.
- W1966178520 cites W2045832089 @default.
- W1966178520 cites W2050956798 @default.
- W1966178520 cites W2051565418 @default.
- W1966178520 cites W2055727674 @default.
- W1966178520 cites W2059694970 @default.
- W1966178520 cites W2073539382 @default.
- W1966178520 cites W2089075018 @default.
- W1966178520 cites W2094313105 @default.
- W1966178520 cites W2101606357 @default.
- W1966178520 cites W2125041035 @default.
- W1966178520 cites W2128075735 @default.
- W1966178520 cites W2155983644 @default.
- W1966178520 cites W2214399572 @default.
- W1966178520 cites W2331594899 @default.
- W1966178520 cites W2950365533 @default.
- W1966178520 cites W2952722604 @default.
- W1966178520 doi "https://doi.org/10.1039/b411014e" @default.
- W1966178520 hasPublicationYear "2004" @default.
- W1966178520 type Work @default.
- W1966178520 sameAs 1966178520 @default.
- W1966178520 citedByCount "25" @default.
- W1966178520 countsByYear W19661785202013 @default.
- W1966178520 countsByYear W19661785202014 @default.
- W1966178520 countsByYear W19661785202017 @default.
- W1966178520 countsByYear W19661785202018 @default.
- W1966178520 countsByYear W19661785202021 @default.
- W1966178520 countsByYear W19661785202023 @default.
- W1966178520 crossrefType "journal-article" @default.
- W1966178520 hasAuthorship W1966178520A5001028688 @default.
- W1966178520 hasAuthorship W1966178520A5057018652 @default.
- W1966178520 hasAuthorship W1966178520A5063594040 @default.
- W1966178520 hasConcept C115624301 @default.
- W1966178520 hasConcept C145148216 @default.
- W1966178520 hasConcept C164866538 @default.
- W1966178520 hasConcept C168900304 @default.
- W1966178520 hasConcept C178790620 @default.
- W1966178520 hasConcept C179104552 @default.
- W1966178520 hasConcept C185592680 @default.
- W1966178520 hasConcept C199360897 @default.
- W1966178520 hasConcept C2778421084 @default.
- W1966178520 hasConcept C32909587 @default.
- W1966178520 hasConcept C41008148 @default.
- W1966178520 hasConcept C544778455 @default.
- W1966178520 hasConcept C8010536 @default.
- W1966178520 hasConcept C96444392 @default.
- W1966178520 hasConceptScore W1966178520C115624301 @default.
- W1966178520 hasConceptScore W1966178520C145148216 @default.
- W1966178520 hasConceptScore W1966178520C164866538 @default.
- W1966178520 hasConceptScore W1966178520C168900304 @default.
- W1966178520 hasConceptScore W1966178520C178790620 @default.
- W1966178520 hasConceptScore W1966178520C179104552 @default.
- W1966178520 hasConceptScore W1966178520C185592680 @default.
- W1966178520 hasConceptScore W1966178520C199360897 @default.
- W1966178520 hasConceptScore W1966178520C2778421084 @default.
- W1966178520 hasConceptScore W1966178520C32909587 @default.
- W1966178520 hasConceptScore W1966178520C41008148 @default.
- W1966178520 hasConceptScore W1966178520C544778455 @default.
- W1966178520 hasConceptScore W1966178520C8010536 @default.
- W1966178520 hasConceptScore W1966178520C96444392 @default.
- W1966178520 hasIssue "24" @default.
- W1966178520 hasLocation W19661785201 @default.
- W1966178520 hasOpenAccess W1966178520 @default.
- W1966178520 hasPrimaryLocation W19661785201 @default.
- W1966178520 hasRelatedWork W1999828662 @default.
- W1966178520 hasRelatedWork W2071574756 @default.