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- W1966189675 abstract "A versatile conversion of methyl methacrylate to methyl 3,3-dialkoxy-2-methylpropanoates proceeds via bromination, then treatment with excess sodium methoxide to yield methyl 3,3-dimethoxy-2-methylpropanoate, which can be transacetalized by treatment with alcohols under acid catalysis to yield the title compounds. Stereoselective chain-extension reactions of these compounds by aldol additions to the aldehydes derived from the ester group (C-1), or by titanium(IV)-mediated allylsilane additions to the acetal carbon (C-3), are examples of the potential utility of methyl 3,3-dialkoxy-2-methylpropanoates to natural products, syntheses." @default.
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- W1966189675 date "1987-01-01" @default.
- W1966189675 modified "2023-10-09" @default.
- W1966189675 title "Synthons for Polyketides: An Improved Synthesis of Methyl 3,3-Dialkoxy-2-methylpropanoates" @default.
- W1966189675 doi "https://doi.org/10.1055/s-1987-28021" @default.
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