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• W1966191640 abstract "The synthesis of four ruthenium phosphonium alkylidene complexes [(H2IMes)Cl2RuCH(PCy3)]+[A]− (1, A = B(C6F5)4; 2, A = BF4; 3, A = OTf; 4, A = BPh4), differing only in the anion is described. The X-ray structures of 1, 3 and 4 show them to be isostructural in the cation, with no interaction between the Ru centers and the anion. Ring closing metathesis of a substrate to a six-membered methylcyclohexene at 0 °C in CD2Cl2 using 1 mol% catalyst, shows that catalysts 1–4 behave very similarly, and exhibit superior activity in comparison to Grubbs second generation and fast-initiating catalysts." @default.
• W1966191640 created "2016-06-24" @default.
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• W1966191640 date "2006-06-01" @default.
• W1966191640 modified "2023-10-09" @default.
• W1966191640 title "Synthesis, characterization and olefin metathesis studies of a family of ruthenium phosphonium alkylidene complexes" @default.
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• W1966191640 doi "https://doi.org/10.1016/j.ica.2005.09.040" @default.
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