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• W1966194628 abstract "We reported controlled synthesis of methacrylic acid, 2-(diethylamino) ethyl methacrylate and 2-acrylamido-2-methyl-1-propa- nesulfonic acid (three electrolyte-type monomers) via reversible addition-fragmentation chain transfer (RAFT) polymerization with the chain transfer agent (CTA) (4-cyanopentanoic acid)-4-dithiobenzoate and initiator (I) 4,4′-azobis(4-cyanovaleric acid) in homogeneous aqueous media. Three distinct [monomer]0: [I]0: [CTA]0 ratios (50:0.2:1, 100:0.2:1, 500:0.2:1) were conducted. The polymerizations exhibited the characteristics of a controlled/“living” polymerization which demonstrated well-controlled molecular weight and low molecular weight distribution. Finally, the results of this investigation were used as a guide for the preparation of a series of well-defined polyelectrolytes (DPn = 50–500, PDI = 1.08–1.17) in high yield." @default.
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• W1966194628 date "2013-01-01" @default.
• W1966194628 modified "2023-10-16" @default.
• W1966194628 title "Controlled Synthesis of Polyelectrolytes by 4-Cyanopentanoic Acid Dithiobenzoate Mediated RAFT Polymerization" @default.
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• W1966194628 doi "https://doi.org/10.1080/10601325.2013.814329" @default.
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