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• W1966196469 abstract "Cu5Sb2O8SiO4 is orthorhombic, space group Pcca, with a = 19.031 (2), b = 9.3944 (6), c = 9.602 (2) Å, and z = 8. Its crystal structure was determined using single crystal X-ray diffraction (R1 = 0.0432 and wR2 = 0.1146). The compound presents a parwelite-like structure. Its anionic three-dimensional framework is built up of corner-sharing SbO6 octahedra and SiO4 tetrahedra, delimiting interconnected channels wherein Cu2+ with different coordination modes, are located. The χM and χMT product versus T plots, showed the Cu5Sb2O8SiO4 material to exhibit an anti-ferromagnetic character with a Neel temperature of about 27 K." @default.
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• W1966196469 date "2007-08-01" @default.
• W1966196469 modified "2023-10-05" @default.
• W1966196469 title "Cu5Sb2O8SiO4, an open framework structure with copper uncommon coordination modes: Cu[2+2+2]O6 and Cu[4+4]O8" @default.
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• W1966196469 doi "https://doi.org/10.1016/j.materresbull.2006.10.028" @default.
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