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- W1966201251 abstract "For poly(9,9-di(6-(2-(3-oxetanyl)butoxyl)hexyl)-2,7-fluorene) (POBOHF), measurements on field induction−thermally stimulated current (FI-TSC) and electroluminescence (EL) under a wide temperature range demonstrate that electric field induction (FI) accompanied by side chain motion can lead to a formation of excimers, which contribute to a growth of a green component in the EL spectrum. This phenomenon also happens to poly(9,9-di-n-octyl-2,7-fluorene) (PFO), especially under long-term operations with higher electric fields (1 × 106 V/cm), copolymers of OBOHF and FO (PF-1/1 and PF-1/3), and even cross-linked POBOHF. The higher polarity of the side chain in the polyfluorenes (PFs) can cause a more pronounced FI effect. For POBOHF, the green component can even dominate after a few cycles of device operation. Lowering the content of cross-linkable commoner in the copolymers from 50 to 25 mol % only moderately suppresses the formation of FI excimers." @default.
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- W1966201251 date "2005-11-24" @default.
- W1966201251 modified "2023-09-26" @default.
- W1966201251 title "Excimer Formation by Electric Field Induction and Side Chain Motion Assistance in Polyfluorenes" @default.
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- W1966201251 doi "https://doi.org/10.1021/ma051594z" @default.
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