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• W1966218664 startingPage "472" @default.
• W1966218664 abstract "A thiofunctional thiazolidine is introduced as a new low‐molar‐mass building block for the introduction of cysteine residues via a thiol‐ene reaction. Allyl‐functional polyglycidol (PG) is used as a model polymer to demonstrate polymer‐analogue functionalization through reaction with the unsaturated side‐chains. A modified trinitrobenzenesulfonic acid (TNBSA) assay is used for the redox‐insensitive quantification and a precise final cysteine content can be predetermined at the polymerization stage. Native chemical ligation at cysteine‐functional PG is performed as a model reaction for a chemoselective peptide modification of this polymer. The three‐step synthesis of the thiofunctional thiazolidine reactant, together with the standard thiol‐ene coupling and the robust quantification assay, broadens the toolbox for thiol‐ene chemistry and offers a generic and straightforward approach to cysteine‐functional materials. image" @default.
• W1966218664 created "2016-06-24" @default.
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• W1966218664 date "2015-01-21" @default.
• W1966218664 modified "2023-10-15" @default.
• W1966218664 title "Cysteine-Functional Polymers via Thiol-ene Conjugation" @default.
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• W1966218664 doi "https://doi.org/10.1002/marc.201400703" @default.
• W1966218664 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/25645319" @default.
• W1966218664 hasPublicationYear "2015" @default.
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