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- W1966238112 abstract "The molecular interactions of MC-540 (Merocyanine 540) in clay suspensions containing natural bentonite and CTAB (cetyl trimethyl ammonium bromide)-modified bentonite were examined by using absorption, steady-state and time-resolved fluorescence spectroscopies. Strong affinity of clays for dye adsorption caused the strong interaction of MC-540 molecules with bentonite particles in aqueous dispersion. The interaction of dye with natural bentonite and CTAB-modified bentonite particles in aqueous dispersion caused significant changes in the photophysical properties of MC-540 when they were compared to those in pure water. Spectral data revealed that monomer, H-dimer and H-aggregate of MC-540 in the clay aqueous dispersions were formed depending on dye concentration. Moreover, H-aggregates of dye were predominantly formed in the CTAB-modified bentonite aqueous suspension. The presence of H-aggregates strongly decreased the fluorescence lifetime of MC-540." @default.
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- W1966238112 date "2015-03-01" @default.
- W1966238112 modified "2023-09-30" @default.
- W1966238112 title "Molecular aggregates of Merocyanine 540 in aqueous suspensions containing natural and CTAB-modified bentonite" @default.
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- W1966238112 doi "https://doi.org/10.1016/j.molstruc.2014.11.046" @default.
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