FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1966254003> ?p ?o ?g. }

• W1966254003 endingPage "958" @default.
• W1966254003 startingPage "958" @default.
• W1966254003 abstract "In-situ X-ray absorption spectroscopy investigations have been carried out to evaluate the oxidation states and the local structure at the Mn, Co and Ni K-edges for LiNi0.65Co0.25Mn0.1O2 during a charging and discharging process in this study. It was found that only the Ni atom in LiNi0.65Co0.25Mn0.1O2 is electroactive from the evolution of XANES spectra and the bond length variation of Ni–O. We observed that the NiII/NiIV and NiIII/NiIV redox pairs exist and the oxidation states of Mn and Co remain as MnIV and CoIII, respectively, in LiNi0.65Co0.25Mn0.1O2 on a charge and discharge cycle. In addition, the irreversible capacity at the first cycle derives mainly from the appearance of inactive Ni during the first discharging, which is consistent with the energy shift E–E0 of the absorption edge for the Ni absorber and the bond length change of Ni–O. A decrease/increase of Debye–Waller factor of the Ni–O contribution results from a decrease/increase of Jahn–Teller active NiIII concentration on the charge and discharge cycle. The charge ordering between NiII and MnIV may take place in this compound, resulting from the significant difference of the bond length and the Debye–Waller factor for the second shell Mn–M and Ni–M contributions between the starting and fully charged states. A balance of the repulsive force and size effect in the layered compound plays an important role in the inhibition of structure distortion during the delithiation and lithiation cycle." @default.
• W1966254003 created "2016-06-24" @default.
• W1966254003 creator A5025162419 @default.
• W1966254003 creator A5030917995 @default.
• W1966254003 creator A5059041682 @default.
• W1966254003 creator A5091379491 @default.
• W1966254003 date "2004-01-01" @default.
• W1966254003 modified "2023-10-16" @default.
• W1966254003 title "In-situ X-ray absorption spectroscopy investigations of a layered LiNi0.65Co0.25Mn0.1O2 cathode material for rechargeable lithium batteries" @default.
• W1966254003 cites W1491792821 @default.
• W1966254003 cites W1526322394 @default.
• W1966254003 cites W1877973172 @default.
• W1966254003 cites W1966292189 @default.
• W1966254003 cites W1978228034 @default.
• W1966254003 cites W1985895439 @default.
• W1966254003 cites W2020841091 @default.
• W1966254003 cites W2029206675 @default.
• W1966254003 cites W2029370916 @default.
• W1966254003 cites W2030083219 @default.
• W1966254003 cites W2061294357 @default.
• W1966254003 cites W2062860882 @default.
• W1966254003 cites W2063422735 @default.
• W1966254003 cites W2074930630 @default.
• W1966254003 cites W2081195017 @default.
• W1966254003 cites W2091840927 @default.
• W1966254003 doi "https://doi.org/10.1039/b315063a" @default.
• W1966254003 hasPublicationYear "2004" @default.
• W1966254003 type Work @default.
• W1966254003 sameAs 1966254003 @default.
• W1966254003 citedByCount "37" @default.
• W1966254003 countsByYear W19662540032012 @default.
• W1966254003 countsByYear W19662540032013 @default.
• W1966254003 countsByYear W19662540032014 @default.
• W1966254003 countsByYear W19662540032015 @default.
• W1966254003 countsByYear W19662540032016 @default.
• W1966254003 countsByYear W19662540032017 @default.
• W1966254003 countsByYear W19662540032018 @default.
• W1966254003 countsByYear W19662540032019 @default.
• W1966254003 countsByYear W19662540032020 @default.
• W1966254003 countsByYear W19662540032021 @default.
• W1966254003 countsByYear W19662540032022 @default.
• W1966254003 countsByYear W19662540032023 @default.
• W1966254003 crossrefType "journal-article" @default.
• W1966254003 hasAuthorship W1966254003A5025162419 @default.
• W1966254003 hasAuthorship W1966254003A5030917995 @default.
• W1966254003 hasAuthorship W1966254003A5059041682 @default.
• W1966254003 hasAuthorship W1966254003A5091379491 @default.
• W1966254003 hasConcept C107861141 @default.
• W1966254003 hasConcept C110715899 @default.
• W1966254003 hasConcept C113196181 @default.
• W1966254003 hasConcept C115624301 @default.
• W1966254003 hasConcept C119824511 @default.
• W1966254003 hasConcept C120665830 @default.
• W1966254003 hasConcept C121332964 @default.
• W1966254003 hasConcept C125287762 @default.
• W1966254003 hasConcept C134018914 @default.
• W1966254003 hasConcept C145148216 @default.
• W1966254003 hasConcept C149635348 @default.
• W1966254003 hasConcept C150244406 @default.
• W1966254003 hasConcept C155860418 @default.
• W1966254003 hasConcept C159985019 @default.
• W1966254003 hasConcept C178790620 @default.
• W1966254003 hasConcept C185592680 @default.
• W1966254003 hasConcept C192562407 @default.
• W1966254003 hasConcept C207114421 @default.
• W1966254003 hasConcept C2778541603 @default.
• W1966254003 hasConcept C2781104464 @default.
• W1966254003 hasConcept C32891209 @default.
• W1966254003 hasConcept C41008148 @default.
• W1966254003 hasConcept C58312451 @default.
• W1966254003 hasConcept C62520636 @default.
• W1966254003 hasConcept C71924100 @default.
• W1966254003 hasConcept C8010536 @default.
• W1966254003 hasConceptScore W1966254003C107861141 @default.
• W1966254003 hasConceptScore W1966254003C110715899 @default.
• W1966254003 hasConceptScore W1966254003C113196181 @default.
• W1966254003 hasConceptScore W1966254003C115624301 @default.
• W1966254003 hasConceptScore W1966254003C119824511 @default.
• W1966254003 hasConceptScore W1966254003C120665830 @default.
• W1966254003 hasConceptScore W1966254003C121332964 @default.
• W1966254003 hasConceptScore W1966254003C125287762 @default.
• W1966254003 hasConceptScore W1966254003C134018914 @default.
• W1966254003 hasConceptScore W1966254003C145148216 @default.
• W1966254003 hasConceptScore W1966254003C149635348 @default.
• W1966254003 hasConceptScore W1966254003C150244406 @default.
• W1966254003 hasConceptScore W1966254003C155860418 @default.
• W1966254003 hasConceptScore W1966254003C159985019 @default.
• W1966254003 hasConceptScore W1966254003C178790620 @default.
• W1966254003 hasConceptScore W1966254003C185592680 @default.
• W1966254003 hasConceptScore W1966254003C192562407 @default.
• W1966254003 hasConceptScore W1966254003C207114421 @default.
• W1966254003 hasConceptScore W1966254003C2778541603 @default.
• W1966254003 hasConceptScore W1966254003C2781104464 @default.
• W1966254003 hasConceptScore W1966254003C32891209 @default.
• W1966254003 hasConceptScore W1966254003C41008148 @default.
• W1966254003 hasConceptScore W1966254003C58312451 @default.
• W1966254003 hasConceptScore W1966254003C62520636 @default.
• W1966254003 hasConceptScore W1966254003C71924100 @default.

• next