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- W1966264910 abstract "A phenyl-terminated organic surface was fabricated by self-assembly of phenyltricosanethiolate monolayers (C6H5(CH2)23SH) on polycrystalline gold substrates. The molecular orientation of the alkyl chain and the phenyl ring was determined by near edge X-ray absorption fine structure spectroscopy (NEXAFS). After chromium deposition a new resonance appeared in the NEXAFS spectra, which could be related to the formation of metal−π sandwich complexes by comparison to reference data recorded for multilayers of bis(benzene)chromium. This conclusion is supported by data recorded using X-ray photoelectron spectroscopy. Experiments carried out with a phenyl-terminated surface fabricated by using a short chain phenylalkanethiol demonstrate that a minimum chain length is required in order to avoid reactions of the deposited metal atoms with the gold substrate and/or with the C−S bonds." @default.
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- W1966264910 date "1997-12-01" @default.
- W1966264910 modified "2023-09-23" @default.
- W1966264910 title "Realization of a Phenyl-Terminated Organic Surface and Its Interaction with Chromium Atoms" @default.
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- W1966264910 doi "https://doi.org/10.1021/la970205u" @default.
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