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• W1966267914 endingPage "399" @default.
• W1966267914 startingPage "393" @default.
• W1966267914 abstract "The effect of hydrostatic pressure on the transition temperature and the hysteresis widths of first order spin crossover phase transitions has been studied. A decrease as well as an increase of the hysteresis width with increasing pressure was reported in the literature. The increase of width with increasing pressure contradicts the expectation derived from mean field theory. We remeasured the pressure dependence of the temperature hysteresis of the compound [Fe(phy)2](BF4)2 (phy=1, 10-phenanthroline-2-carbaldehydephenylhydrazone). The spin transition temperatures at ambient temperature are T↑1/2=289±1K, T↓1/2=283±1K. An increase of the hysteresis width of dΔT1/2/dp=0.29Kkbar−1 up to p=4.1 kbar has been measured confirming the reported anomaly. The change of the average temperatures T1/2=1/2(T↑1/2+T↓1/2) at which the high spin fraction γ is 1/2 is determined to be 3.0±0.2 K kbar−1. Allowing for a pressure dependence of the bulk modulus of the compound, the anomalous increase of hysteresis width can be interpreted." @default.
• W1966267914 created "2016-06-24" @default.
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• W1966267914 date "1999-03-01" @default.
• W1966267914 modified "2023-10-13" @default.
• W1966267914 title "The influence of hydrostatic pressure on hysteresis phase transition in spin crossover compounds" @default.
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• W1966267914 doi "https://doi.org/10.1016/s0022-3697(98)00259-5" @default.
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