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- W1966273896 abstract "A series of β-diketiminate-supported magnesium and calcium acetylide complexes have been synthesized by σ-bond metathesis of magnesium n-butyl or magnesium and calcium amido precursors and a range of terminal acetylenes. The dimeric complexes have been characterized by NMR spectroscopy and X-ray diffraction analysis. The homoleptic bis(amido) and dialkyl complexes [M{X(SiMe3)2}2(THF)2] (M = Ca, Sr; X = N, CH) have been assessed for the atom-efficient, catalytic head-to-head dimerization of donor-functionalized terminal alkynes into butatrienes and aryl-/silyl-substituted terminal acetylenes into 1,3-enynes. Deuterium labeling studies of the catalytic reactions are suggested to imply that triene formation requires concerted proton delivery and rearrangement via an adjacent methylene group at a bimetallic alkaline-earth species." @default.
- W1966273896 created "2016-06-24" @default.
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- W1966273896 date "2013-08-22" @default.
- W1966273896 modified "2023-10-03" @default.
- W1966273896 title "Catalytic and Stoichiometric Cumulene Formation within Dimeric Group 2 Acetylides" @default.
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- W1966273896 doi "https://doi.org/10.1021/om400678d" @default.
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