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• W1966277533 endingPage "355" @default.
• W1966277533 startingPage "350" @default.
• W1966277533 abstract "Co-liquefaction of micro algae (Chlorella, Spirulina, and Littorale) with coal (Australian Yallourn brown coal and Illinois No. 6 coal) was carried out under pressurized H2 in 1-methylnaphthalene at 350−400 °C for 60 min with various catalysts. Co-liquefaction of Chlorella with Yallourn coal was successfully achieved with excess sulfur to iron (S/Fe = 4), where sufficient amount of Fe1-xS, which is believed to be the active species in the coal liquefaction, was produced. The conversion and the yield of the hexane-soluble fraction were close to the values calculated from the additivity of the product yields of the respective homo-reactions. In the reaction with a one-to-one mixture of Chlorella and Yallourn coal, 99.8% of conversion and 65.5% of hexane-soluble fraction were obtained at 400 °C with Fe(CO)5 at S/Fe = 4. When Littorale and Spirulina were used as micro algae, a similar tendency was observed with the iron catalyst. On the other hand, in the co-liquefaction with Illinois No. 6 coal, which is known to contain a large amount of sulfur in the form of catalytically active pyrite, the oil yield in the co-liquefaction was close to the additivity of the respective reaction with Fe(CO)5−S, even at S/Fe = 2. Ru3(CO)12 was also effective for the co-liquefaction of micro algae with coal." @default.
• W1966277533 created "2016-06-24" @default.
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• W1966277533 date "2001-01-25" @default.
• W1966277533 modified "2023-10-13" @default.
• W1966277533 title "Co-liquefaction of Micro Algae with Coal Using Coal Liquefaction Catalysts" @default.
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• W1966277533 doi "https://doi.org/10.1021/ef000129u" @default.
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