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• W1966297712 endingPage "639" @default.
• W1966297712 startingPage "634" @default.
• W1966297712 abstract "Intra-5f fluorescence from crystalline needles of Cs2Np(VI)O2Cl4 has been observed in the near-infrared at room temperature following continuous wave excitation at 633 nm. Characterization of the molecular structure of Cs2Np(VI)O2Cl4 by single-crystal X-ray diffraction analysis is reported. The observed emission originates from an excited state approximately 6889 cm−1 above the ground state. The vibronic structure in the emission spectrum is assigned based on comparison with the analyses of liquid helium absorption spectra of Cs2U(Np)O2Cl4 published by Denning et al. and room temperature fluorescence data of Cs2U(Np)O2Cl4 reported by Wilkerson et al. The room temperature fluorescence lifetime of the observed origin of Cs2NpO2Cl4 is compared with lifetime data from the doped system, Cs2U(Np)O2Cl4." @default.
• W1966297712 created "2016-06-24" @default.
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• W1966297712 date "2007-10-01" @default.
• W1966297712 modified "2023-10-02" @default.
• W1966297712 title "Crystal structure and spectroscopic measurements of room temperature intra-5f fluorescence of Cs2Np(VI)O2Cl4" @default.
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• W1966297712 doi "https://doi.org/10.1016/j.jallcom.2006.12.011" @default.
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