Matches in SemOpenAlex for { <https://semopenalex.org/work/W1966317577> ?p ?o ?g. }
Showing items 1 to 71 of
71
with 100 items per page.
- W1966317577 endingPage "764" @default.
- W1966317577 startingPage "761" @default.
- W1966317577 abstract "Dependent on the mode of preparation, 2-hydroxyethyl methacrylate (HEMA) can at low temperatures acquire either vitreous or crystalline states. On heating γ-irradiated vitreous HEMA, polymerization starts immediately after transition of the system from the vitreous state to that of a supercooled liquid (Tg = 177 K). This provides conditions for growth of polymer chains and suppression of bimolecular termination of active growing centres. Polymerization of radiated crystalline HEMA occurs at higher temperatures in the monomer melting region. At equal dosages of preliminary radiation, the transformation depth for the crystalline sample is considerably lower than that for the vitreous sample; this effect is due to different molecular mobilities in heated crystalline and vitreous samples. In HEMA post-polymerization, the very early transformation stages yielded an insoluble cross-linked polymer. This paper discusses the possible mechanism of cross-linking during polymerization of monomers of the HEMA type as a result of detachment of hydrogen from the carbon atom in the glycol group." @default.
- W1966317577 created "2016-06-24" @default.
- W1966317577 creator A5059162554 @default.
- W1966317577 creator A5060925943 @default.
- W1966317577 creator A5069773907 @default.
- W1966317577 date "1979-01-01" @default.
- W1966317577 modified "2023-10-08" @default.
- W1966317577 title "A study of post-radiation polymerization of 2-hydroxyethyl methacrylate γ-irradiated in crystalline and vitreous states" @default.
- W1966317577 cites W2011756564 @default.
- W1966317577 cites W2014441095 @default.
- W1966317577 cites W2042177724 @default.
- W1966317577 cites W2081647113 @default.
- W1966317577 cites W2089847164 @default.
- W1966317577 cites W2109873473 @default.
- W1966317577 cites W2143222848 @default.
- W1966317577 cites W2163484628 @default.
- W1966317577 doi "https://doi.org/10.1016/0014-3057(79)90028-4" @default.
- W1966317577 hasPublicationYear "1979" @default.
- W1966317577 type Work @default.
- W1966317577 sameAs 1966317577 @default.
- W1966317577 citedByCount "5" @default.
- W1966317577 countsByYear W19663175772023 @default.
- W1966317577 crossrefType "journal-article" @default.
- W1966317577 hasAuthorship W1966317577A5059162554 @default.
- W1966317577 hasAuthorship W1966317577A5060925943 @default.
- W1966317577 hasAuthorship W1966317577A5069773907 @default.
- W1966317577 hasConcept C111337013 @default.
- W1966317577 hasConcept C121332964 @default.
- W1966317577 hasConcept C122865956 @default.
- W1966317577 hasConcept C132050475 @default.
- W1966317577 hasConcept C15487406 @default.
- W1966317577 hasConcept C159985019 @default.
- W1966317577 hasConcept C166940927 @default.
- W1966317577 hasConcept C185544564 @default.
- W1966317577 hasConcept C188027245 @default.
- W1966317577 hasConcept C192562407 @default.
- W1966317577 hasConcept C44228677 @default.
- W1966317577 hasConcept C521977710 @default.
- W1966317577 hasConceptScore W1966317577C111337013 @default.
- W1966317577 hasConceptScore W1966317577C121332964 @default.
- W1966317577 hasConceptScore W1966317577C122865956 @default.
- W1966317577 hasConceptScore W1966317577C132050475 @default.
- W1966317577 hasConceptScore W1966317577C15487406 @default.
- W1966317577 hasConceptScore W1966317577C159985019 @default.
- W1966317577 hasConceptScore W1966317577C166940927 @default.
- W1966317577 hasConceptScore W1966317577C185544564 @default.
- W1966317577 hasConceptScore W1966317577C188027245 @default.
- W1966317577 hasConceptScore W1966317577C192562407 @default.
- W1966317577 hasConceptScore W1966317577C44228677 @default.
- W1966317577 hasConceptScore W1966317577C521977710 @default.
- W1966317577 hasIssue "8" @default.
- W1966317577 hasLocation W19663175771 @default.
- W1966317577 hasOpenAccess W1966317577 @default.
- W1966317577 hasPrimaryLocation W19663175771 @default.
- W1966317577 hasRelatedWork W1215773549 @default.
- W1966317577 hasRelatedWork W188865736 @default.
- W1966317577 hasRelatedWork W1970794896 @default.
- W1966317577 hasRelatedWork W1974540658 @default.
- W1966317577 hasRelatedWork W2025678239 @default.
- W1966317577 hasRelatedWork W2069269787 @default.
- W1966317577 hasRelatedWork W2084238422 @default.
- W1966317577 hasRelatedWork W2090872226 @default.
- W1966317577 hasRelatedWork W2361180459 @default.
- W1966317577 hasRelatedWork W4233129430 @default.
- W1966317577 hasVolume "15" @default.
- W1966317577 isParatext "false" @default.
- W1966317577 isRetracted "false" @default.
- W1966317577 magId "1966317577" @default.
- W1966317577 workType "article" @default.