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- W1966367076 abstract "We investigate high-pressure induced phase transitions of YF3 and Eu-doped YF3 (YF3:Eu3+) by using the angular dispersive synchrotron X-ray diffraction technique at room temperature. It is found that the starting orthorhombic phase transforms into a new high-pressure phase which is identified as hexagonal structure in both YF3 and YF3:Eu3+. The high-pressure structure of YF3 and YF3:Eu3+ returned to the orthorhombic phase after release of pressure. The photoluminescence properties of YF3:Eu3+ have also been studied under high pressure up to 25 GPa. The Eu3+ ion luminescence lines of 5D0 → 7F1,2,3,4 transition originating from the orthorhombic phase transform into another group of luminescence lines of hexagonal phase under high pressure, which reveals the pressure-induced structural transition of YF3:Eu3+. The relative luminescence intensity ratio of 5D0 → 7F2 to 5D0 → 7F1 transitions of the Eu3+ ions is found to increase with increasing pressure before phase transition and decrease after transition finished, indicating reducing and enhancing of the symmetry around the Eu3+ ions, respectively." @default.
- W1966367076 created "2016-06-24" @default.
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- W1966367076 date "2013-01-01" @default.
- W1966367076 modified "2023-09-24" @default.
- W1966367076 title "Structural phase transition and photoluminescence properties of YF3 and YF3:Eu3+ under high pressure" @default.
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- W1966367076 doi "https://doi.org/10.1039/c3cp53230e" @default.
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