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- W1966367104 abstract "The palladium Liii absorption spectra of complex compounds K2PdCl6, K2PdCl4, (NH4)2PdCl4, and trans‐[Pd(NH3)2Cl2] have been measured with a 50 cm bent‐quartz crystal vacuum spectrograph. A strong ‘‘white line’’ has been found at the absorption threshold and a few weak structures have been observed in the energy range of about 20 eV above the white line. These absorption structures have been interpreted in terms of molecular‐orbital (MO) theory. The Pd Liii absorption spectrum of trans‐[Pd(NH3)2Cl2] is somewhat different from those of K2PdCl4 and (NH4)2PdCl4 which are quite alike. The white line of K2PdCl6 shifts by 2.0 eV toward higher energies relative to that of K2PdCl4 or (NH4)2PdCl4. This chemical shift is due to the difference of the oxidation states of the palladium ions Pd2+ and Pd4+." @default.
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- W1966367104 date "1985-03-01" @default.
- W1966367104 modified "2023-09-24" @default.
- W1966367104 title "Palladium Liii x‐ray absorption‐edge structures of K2PdCl6, K2PdCl4, (NH4)2PdCl4, and trans‐[Pd(NH3)2Cl2]" @default.
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- W1966367104 doi "https://doi.org/10.1063/1.448361" @default.
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