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- W1966369062 abstract "The two coordination polymers [Ni(ndc)(lutidine)2(H2O)2], CPO-3, and [Ni3(ndc)3(pyridine)4], CPO-4, were obtained by hydrothermal reactions between 2,6-naphthalenedicarboxylic acid (ndc), 3,4-lutidine and nickel(II) nitrate (CPO-3) and ndc, pyridine and nickel(II) nitrate (CPO-4), respectively. In CPO-3, the combination of octahedral nickel(II) ions and ndc ligands leads to the formation of infinite chains. CPO-4 is based on linear trinuclear building units of octahedral nickel(II) ions that are crosslinked via the ndc ligands to form a 3D-structure. The crystal structure of CPO-3 was solved from synchrotron powder X-ray data, while the crystal structure of CPO-4 was solved from conventional single-crystal X-ray data. Crystal data for CPO-3: monoclinic space group Cc (No. 9), a=14.8583(2), b=20.3985(3), c=10.7258(1) Å, β=129.0067(6)°, V=2526.14(5) Å3 and Z=4. Crystal data for CPO-4: monoclinic space group P21/c (No. 14), a=11.491(3), b=17.917(4), c=12.781(3) Å, β=116.142(7)°, V=2362.2(9) Å3 and Z=2. The thermal and magnetic properties of both compounds were investigated." @default.
- W1966369062 created "2016-06-24" @default.
- W1966369062 creator A5031433543 @default.
- W1966369062 creator A5048080494 @default.
- W1966369062 date "2003-02-01" @default.
- W1966369062 modified "2023-10-16" @default.
- W1966369062 title "Novel coordination polymers based on nickel(II) and 2,6-naphthalenedicarboxylate" @default.
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- W1966369062 doi "https://doi.org/10.1016/s1293-2558(03)00005-0" @default.
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