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• W1966376987 abstract "$^{31}mathrm{P}$ NMR spectroscopy is used to study the nature of the molecular dynamics in a P-doped molecular As sulfide glass in the region of glass transition. Isotropic tumbling of the constituent molecules in the glass is observed even at $ensuremath{sim}70phantom{rule{0.3em}{0ex}}mathrm{K}$ below glass transition temperature, indicating an anomalously strong decoupling of this motion from viscosity and diffusion. The presence of such dynamic orientational disorder at temperatures where the positional disorder is likely to be nearly frozen in is unusual in molecular glass formers and may have important implications in understanding the thermodynamic vs dynamic origin of glass transition." @default.
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• W1966376987 date "2007-12-13" @default.
• W1966376987 modified "2023-10-16" @default.
• W1966376987 title "Anomalously large decoupling of rotational and shear relaxation in a molecular glass" @default.
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• W1966376987 doi "https://doi.org/10.1103/physrevb.76.214202" @default.
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