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- W1966382013 abstract "We propose an experimental method to confirm theoretical predictions concerning the detection of phase transitions in solids via the measurement of the chemical potential as a function of temperature. Here, as experimental evidence of the validity of these predictions, we perform indirect measurements of the chemical potential vs temperature for Gd, Cr, and TiNi samples by means of an electrochemical experiment. This made it possible to easily localize all critical temperatures connected either with magnetic phase transitions $[{T}_{mathrm{C}}$ (Gd), ${T}_{mathrm{N}}$ (Cr)] or structural phase transformations in the shape-memory alloy NiTi. The values of the critical temperatures, obtained in this way remain in exceptionally good agreement with the results of the auxiliary heat flow measurements and the existing literature data concerning critical temperatures. We hope that further development of the experimental techniques, based on chemical potential measurements, can provide a new experimental tool in the search for phase transitions (induced by temperature, pressure, concentration, etc.) in real materials, regardless of the type of phase transitions and irrespective of the underlying mechanism." @default.
- W1966382013 created "2016-06-24" @default.
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- W1966382013 date "2001-01-10" @default.
- W1966382013 modified "2023-09-27" @default.
- W1966382013 title "Experimental method to detect phase transitions via the chemical potential" @default.
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- W1966382013 doi "https://doi.org/10.1103/physrevb.63.052101" @default.
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