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- W1966396052 abstract "Rietveld analysis of neutron powder diffraction patterns from niobium dioxide at 295 and 1300 K have been performed. At 1300 K NbO2 adopts a rutile-type structure (P42/mnm, a = 4.8463 Å, c = 3.0315 Å, x = 0.2924), whereas the room temperature form can be described as a superstructure with a subcell of the rutile type (I41/a, a = 13.7020 Å, c = 5.9850 Å). Both the c axis and the oxygen position parameter in the rutile phase are anomalously small compared with other rutile dioxides. This can be rationalized in terms of M-M bonding. Both the niobium and the oxygen thermal displacement are large in the rutile phase." @default.
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- W1966396052 date "1994-11-01" @default.
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- W1966396052 title "A Powder Neutron Diffraction Study of Semiconducting and Metallic Niobium Dioxide" @default.
- W1966396052 doi "https://doi.org/10.1006/jssc.1994.1334" @default.
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