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• W1966403765 endingPage "3559" @default.
• W1966403765 startingPage "3554" @default.
• W1966403765 abstract "Synthesis and structural characterization of the first LiFeO2 compound with tetrahedrally coordinated Fe3+ is reported. When used as a positive intercalation electrode in a lithium cell, it can store charge of up to 120 mAhg-1 at a rate of 100 mAg-1. However, it converts to the defect spinel LiFe5O8 on cycling. By combining results from powder X-ray diffraction, differential electrochemical mass spectrometry, electrochemical cycling, and TG-MS, it is shown that such conversion, which involved oxygen loss, is not associated with direct O2 gas evolution but instead reaction with the electrolyte. We suggest that intercalation/deintercalation is accompanied by the exchange of Li+ by H+ in the material and subsequent loss of H2O, thus converting LiFeO2 to the defect spinel LiFe5O8 on cycling." @default.
• W1966403765 created "2016-06-24" @default.
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• W1966403765 date "2008-02-20" @default.
• W1966403765 modified "2023-09-25" @default.
• W1966403765 title "Synthesis of Tetrahedral LiFeO₂ and Its Behavior as a Cathode in Rechargeable Lithium Batteries" @default.
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• W1966403765 doi "https://doi.org/10.1021/ja077651g" @default.
• W1966403765 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/18284239" @default.
• W1966403765 hasPublicationYear "2008" @default.
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