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• W1966427771 endingPage "11961" @default.
• W1966427771 startingPage "11956" @default.
• W1966427771 abstract "Triangular halogen trimers (RX)3, where X = Br, I and R represents H, H3C, H2FC, HF2C, F3C, CH2=CH, CH[triple bond]C, and Ph, have been investigated using the density functional theory in the Perdew, Burke, and Ernzerhof method. We report herein the optimized geometries of the stable structures, their vibrational frequencies, and binding energies with the two- and three-body terms. All trimer structures possess a cyclic array of halogen atoms in the type II approach by virtue of the nonspherical atomic charge distribution around the halogens. The Br...Br interactions in trimers are very weak, whereas the I...I interactions in trimers are relatively stronger. While all bromine trimers and most of iodine trimers are predicted to be noncooperative, three of iodine trimers show weak cooperativity. The analysis of vibration modes reveals that all halogen trimers exhibit no especially remarkable frequency shifts. It is also shown that the electrostatic contribution plays a major role in the halogen...halogen interactions in halogen trimers. In contrast to bromine trimers, the relative contribution of charge-transfer component to the halogen...halogen interactions becomes more important for iodine trimers." @default.
• W1966427771 created "2016-06-24" @default.
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• W1966427771 date "2005-12-01" @default.
• W1966427771 modified "2023-10-10" @default.
• W1966427771 title "Triangular Halogen Trimers. A DFT Study of the Structure, Cooperativity, and Vibrational Properties" @default.
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• W1966427771 doi "https://doi.org/10.1021/jp0547360" @default.
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