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- W1966442012 abstract "Garlic and onion, are well known for their medical value, especially in against cancer and anticardiovacular diseases. Alliins (S-alk(en)yl-L-cysteine sulphoxides) are sources of major active compounds in Allium plants. Se incorporation into garlic significantly increases activities of garlic in cancer prevention and inhibition. Selenomethionine, selenocysteine and Se-methylselenocysteine have been identified in garlic and onion. Previously we identified gamma-glutamyl-Se-methyl-L-selenocysteine, in extracts of garlic cultivated in Se-rich soil [Med. Res. Rev. 16 (1) (1996) 111], suggesting the possible existence of Se-alk(en)yl-L-cysteine selenoxides (Se-alliins) in garlic. Several comparative experiments were carried out to demonstrate the existence of Se-alliins in Se-enriched garlic and onion. We found that there was one similar time-dependent Se signal in HPLC-inductively coupled plasma MS chromatograms of cold-water extracts of freeze-dried garlic powder and fresh garlic. This signal was lost when the extracts of garlic powder and fresh garlic were stored for 1 day at >4 degrees C, but remained in fresh onion extract at the same storage conditions. These phenomena and possible mechanisms are discussed. An additional experiment showed that Allium species cultivated in Se-rich soil might contain two different Se-alliins." @default.
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- W1966442012 date "2004-04-01" @default.
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- W1966442012 title "High-performance liquid chromatographic–inductively coupled plasma mass spectrometric evidence for Se-“alliins” in garlic and onion grown in Se-rich soil" @default.
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- W1966442012 doi "https://doi.org/10.1016/j.chroma.2003.11.077" @default.
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