Matches in SemOpenAlex for { <https://semopenalex.org/work/W1966447534> ?p ?o ?g. }
Showing items 1 to 92 of
92
with 100 items per page.
- W1966447534 endingPage "14" @default.
- W1966447534 startingPage "9" @default.
- W1966447534 abstract "The absorption and fluorescence spectra, fluorescence quantum yields and lifetimes of 3-cyano-4-furyl-6-phenyl-2-(9-anthralylidene)-pyridine (FPAP) in various solvents are reported. The results show that the quantum yield of the fluorescence (Φf) of FPAP is high and decreased with increasing solvent polarity. The fluorescence decay time is almost single exponential, independent of the excitation wavelength and its value decreases upon increasing the solvent polarity. The radiative rate constant (kr), however, shows a maximum value for solvents of intermediate polarity, e.g. in CHCl3 a value of 2.1×108 s−1 is attained. However, knr value increases with increasing solvent polarity. The bathochromic shift of the emission spectra and the resulting increase in the excited state dipole moment indicate the charge transfer (CT) character of the emitting singlet state of FPAP. The relatively large values of kr and the corresponding transition dipole moment (Mf) indicate the absence of a twist intramolecular charge transfer in the fluorescent states." @default.
- W1966447534 created "2016-06-24" @default.
- W1966447534 creator A5090925754 @default.
- W1966447534 date "2000-10-01" @default.
- W1966447534 modified "2023-09-27" @default.
- W1966447534 title "Photoinduced intramolecular charge transfer of 3-cyano-4-furyl-6-phenyl-2-(9-anthralylidene)-pyridine" @default.
- W1966447534 cites W133052044 @default.
- W1966447534 cites W1981032442 @default.
- W1966447534 cites W1981554467 @default.
- W1966447534 cites W1983229796 @default.
- W1966447534 cites W1984510177 @default.
- W1966447534 cites W1991527977 @default.
- W1966447534 cites W1994228218 @default.
- W1966447534 cites W2001323304 @default.
- W1966447534 cites W2001768227 @default.
- W1966447534 cites W2002438953 @default.
- W1966447534 cites W2005970157 @default.
- W1966447534 cites W2017570371 @default.
- W1966447534 cites W2038495807 @default.
- W1966447534 cites W2039234588 @default.
- W1966447534 cites W2041931011 @default.
- W1966447534 cites W2045854837 @default.
- W1966447534 cites W2050270322 @default.
- W1966447534 cites W2073638837 @default.
- W1966447534 cites W2078427474 @default.
- W1966447534 cites W2089460896 @default.
- W1966447534 cites W2496393867 @default.
- W1966447534 doi "https://doi.org/10.1016/s1010-6030(00)00336-1" @default.
- W1966447534 hasPublicationYear "2000" @default.
- W1966447534 type Work @default.
- W1966447534 sameAs 1966447534 @default.
- W1966447534 citedByCount "8" @default.
- W1966447534 countsByYear W19664475342014 @default.
- W1966447534 countsByYear W19664475342020 @default.
- W1966447534 countsByYear W19664475342022 @default.
- W1966447534 crossrefType "journal-article" @default.
- W1966447534 hasAuthorship W1966447534A5090925754 @default.
- W1966447534 hasConcept C119824511 @default.
- W1966447534 hasConcept C121332964 @default.
- W1966447534 hasConcept C132439834 @default.
- W1966447534 hasConcept C171001562 @default.
- W1966447534 hasConcept C173523689 @default.
- W1966447534 hasConcept C178790620 @default.
- W1966447534 hasConcept C181500209 @default.
- W1966447534 hasConcept C184779094 @default.
- W1966447534 hasConcept C185592680 @default.
- W1966447534 hasConcept C2779485729 @default.
- W1966447534 hasConcept C2780471494 @default.
- W1966447534 hasConcept C46051903 @default.
- W1966447534 hasConcept C62520636 @default.
- W1966447534 hasConcept C71240020 @default.
- W1966447534 hasConcept C75079739 @default.
- W1966447534 hasConcept C75473681 @default.
- W1966447534 hasConcept C91881484 @default.
- W1966447534 hasConceptScore W1966447534C119824511 @default.
- W1966447534 hasConceptScore W1966447534C121332964 @default.
- W1966447534 hasConceptScore W1966447534C132439834 @default.
- W1966447534 hasConceptScore W1966447534C171001562 @default.
- W1966447534 hasConceptScore W1966447534C173523689 @default.
- W1966447534 hasConceptScore W1966447534C178790620 @default.
- W1966447534 hasConceptScore W1966447534C181500209 @default.
- W1966447534 hasConceptScore W1966447534C184779094 @default.
- W1966447534 hasConceptScore W1966447534C185592680 @default.
- W1966447534 hasConceptScore W1966447534C2779485729 @default.
- W1966447534 hasConceptScore W1966447534C2780471494 @default.
- W1966447534 hasConceptScore W1966447534C46051903 @default.
- W1966447534 hasConceptScore W1966447534C62520636 @default.
- W1966447534 hasConceptScore W1966447534C71240020 @default.
- W1966447534 hasConceptScore W1966447534C75079739 @default.
- W1966447534 hasConceptScore W1966447534C75473681 @default.
- W1966447534 hasConceptScore W1966447534C91881484 @default.
- W1966447534 hasIssue "1" @default.
- W1966447534 hasLocation W19664475341 @default.
- W1966447534 hasOpenAccess W1966447534 @default.
- W1966447534 hasPrimaryLocation W19664475341 @default.
- W1966447534 hasRelatedWork W1969365692 @default.
- W1966447534 hasRelatedWork W1974272036 @default.
- W1966447534 hasRelatedWork W1979424184 @default.
- W1966447534 hasRelatedWork W1980371198 @default.
- W1966447534 hasRelatedWork W1983973965 @default.
- W1966447534 hasRelatedWork W1995019591 @default.
- W1966447534 hasRelatedWork W2306811943 @default.
- W1966447534 hasRelatedWork W2949272676 @default.
- W1966447534 hasRelatedWork W3003068284 @default.
- W1966447534 hasRelatedWork W2066414010 @default.
- W1966447534 hasVolume "137" @default.
- W1966447534 isParatext "false" @default.
- W1966447534 isRetracted "false" @default.
- W1966447534 magId "1966447534" @default.
- W1966447534 workType "article" @default.